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In this book, the performance of homogeneous and heterogeneous catalysts applied in biomass processing was assessed, paying special attention to the main advantages and challenges related to their use. Indeed, these challenges are opportunities to develop new research lines that could be fruitful in the near future. Thus, different studies are included, dealing with diverse subjects, with one main goal in common: the improvement of different aspects related to biomass processing through the use of catalysts.
Book Synopsis Biomass Derived Heterogeneous and Homogeneous Catalysts by : José María Encinar Martín
Download or read book Biomass Derived Heterogeneous and Homogeneous Catalysts written by José María Encinar Martín and published by MDPI. This book was released on 2021-06-09 with total page 200 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this book, the performance of homogeneous and heterogeneous catalysts applied in biomass processing was assessed, paying special attention to the main advantages and challenges related to their use. Indeed, these challenges are opportunities to develop new research lines that could be fruitful in the near future. Thus, different studies are included, dealing with diverse subjects, with one main goal in common: the improvement of different aspects related to biomass processing through the use of catalysts.
In this book, the performance of homogeneous and heterogeneous catalysts applied in biomass processing was assessed, paying special attention to the main advantages and challenges related to their use. Indeed, these challenges are opportunities to develop new research lines that could be fruitful in the near future. Thus, different studies are included, dealing with diverse subjects, with one main goal in common: the improvement of different aspects related to biomass processing through the use of catalysts.
Book Synopsis Biomass Derived Heterogeneous and Homogeneous Catalysts by : José María Encinar Martín
Download or read book Biomass Derived Heterogeneous and Homogeneous Catalysts written by José María Encinar Martín and published by . This book was released on 2021 with total page 200 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this book, the performance of homogeneous and heterogeneous catalysts applied in biomass processing was assessed, paying special attention to the main advantages and challenges related to their use. Indeed, these challenges are opportunities to develop new research lines that could be fruitful in the near future. Thus, different studies are included, dealing with diverse subjects, with one main goal in common: the improvement of different aspects related to biomass processing through the use of catalysts.
This Special Issue, titled "Biomass Derived Heterogeneous and Homogeneous Catalysts, 2nd Edition", includes topics such as converting biomass to energy and value-added products, green technology, the circular economy, sustainability, and the role of catalysts. Catalytic performance, reusability, and characteristics are covered extensively.
Book Synopsis Biomass Derived Heterogeneous and Homogeneous Catalysts, 2nd Edition by : José María Encinar Martín
Download or read book Biomass Derived Heterogeneous and Homogeneous Catalysts, 2nd Edition written by José María Encinar Martín and published by . This book was released on 2024-06-17 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This Special Issue, titled "Biomass Derived Heterogeneous and Homogeneous Catalysts, 2nd Edition", includes topics such as converting biomass to energy and value-added products, green technology, the circular economy, sustainability, and the role of catalysts. Catalytic performance, reusability, and characteristics are covered extensively.
Advanced Functional Solid Catalysts for Biomass Valorization presents the basic concepts in catalysis (homogeneous, heterogeneous, and enzymatic) and the properties of various kinds of heterogeneous solid catalysts, including their structure, porosity, particle size, BET surface area, acid-base, and redox properties. Useful information about biorefineries, types of biomass feedstocks, their structures and properties as well as about several potential catalytic routes for biomass upgrading to useful fuels and chemicals is provided in this book. Importantly, this book covers the most recent developments toward functionalization of various solid catalysts, optimization of catalysts' properties, developing cascade catalytic strategies, exploring reaction kinetics/mechanisms, and evaluating catalysts' stability/reusability during biomass upgrading. Current challenges and opportunities for the future biorefineries as well as for the design of advanced functional solid catalysts are critically discussed. Describes catalysis as a promising technology for the development of eco-friendly and economically viable strategies for several important energy and environmental applications. Covers heterogeneous solid catalysts because of their versatile benefits in terms of catalysts' synthesis, production cost, stability, and reusability as compared to homogeneous liquid catalysts. Provides promising strategies for the design of new catalytic materials, such as carbon materials, metal-organic frameworks, zeolites, and mesoporous silicas. Describes functional solid catalysts for developing one-pot cascade processes for efficient biomass valorization and other vital chemical transformations.
Book Synopsis Advanced Functional Solid Catalysts for Biomass Valorization by : Chaudhery Mustansar Hussain
Download or read book Advanced Functional Solid Catalysts for Biomass Valorization written by Chaudhery Mustansar Hussain and published by Elsevier. This book was released on 2020-06-14 with total page 274 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advanced Functional Solid Catalysts for Biomass Valorization presents the basic concepts in catalysis (homogeneous, heterogeneous, and enzymatic) and the properties of various kinds of heterogeneous solid catalysts, including their structure, porosity, particle size, BET surface area, acid-base, and redox properties. Useful information about biorefineries, types of biomass feedstocks, their structures and properties as well as about several potential catalytic routes for biomass upgrading to useful fuels and chemicals is provided in this book. Importantly, this book covers the most recent developments toward functionalization of various solid catalysts, optimization of catalysts' properties, developing cascade catalytic strategies, exploring reaction kinetics/mechanisms, and evaluating catalysts' stability/reusability during biomass upgrading. Current challenges and opportunities for the future biorefineries as well as for the design of advanced functional solid catalysts are critically discussed. Describes catalysis as a promising technology for the development of eco-friendly and economically viable strategies for several important energy and environmental applications. Covers heterogeneous solid catalysts because of their versatile benefits in terms of catalysts' synthesis, production cost, stability, and reusability as compared to homogeneous liquid catalysts. Provides promising strategies for the design of new catalytic materials, such as carbon materials, metal-organic frameworks, zeolites, and mesoporous silicas. Describes functional solid catalysts for developing one-pot cascade processes for efficient biomass valorization and other vital chemical transformations.
Compiled by a well-known expert in the field, Liquid Biofuels provides a profound knowledge to researchers about biofuel technologies, selection of raw materials, conversion of various biomass to biofuel pathways, selection of suitable methods of conversion, design of equipment, selection of operating parameters, determination of chemical kinetics, reaction mechanism, preparation of bio-catalyst: its application in bio-fuel industry and characterization techniques, use of nanotechnology in the production of biofuels from the root level to its application and many other exclusive topics for conducting research in this area. Written with the objective of offering both theoretical concepts and practical applications of those concepts, Liquid Biofuels can be both a first-time learning experience for the student facing these issues in a classroom and a valuable reference work for the veteran engineer or scientist. The description of the detailed characterization methodologies along with the precautions required during analysis are extremely important, as are the detailed description about the ultrasound assisted biodiesel production techniques, aviation biofuels and its characterization techniques, advance in algal biofuel techniques, pre-treatment of biomass for biofuel production, preparation and characterization of bio-catalyst, and various methods of optimization. The book offers a comparative study between the various liquid biofuels obtained from different methods of production and its engine performance and emission analysis so that one can get the utmost idea to find the better biofuel as an alternative fuel. Since the book covers almost all the field of liquid biofuel production techniques, it will provide advanced knowledge to the researcher for practical applications across the energy sector. A valuable reference for engineers, scientists, chemists, and students, this volume is applicable to many different fields, across many different industries, at all levels. It is a must-have for any library.
Book Synopsis Liquid Biofuels by : Krushna Prasad Shadangi
Download or read book Liquid Biofuels written by Krushna Prasad Shadangi and published by John Wiley & Sons. This book was released on 2021-06-29 with total page 754 pages. Available in PDF, EPUB and Kindle. Book excerpt: Compiled by a well-known expert in the field, Liquid Biofuels provides a profound knowledge to researchers about biofuel technologies, selection of raw materials, conversion of various biomass to biofuel pathways, selection of suitable methods of conversion, design of equipment, selection of operating parameters, determination of chemical kinetics, reaction mechanism, preparation of bio-catalyst: its application in bio-fuel industry and characterization techniques, use of nanotechnology in the production of biofuels from the root level to its application and many other exclusive topics for conducting research in this area. Written with the objective of offering both theoretical concepts and practical applications of those concepts, Liquid Biofuels can be both a first-time learning experience for the student facing these issues in a classroom and a valuable reference work for the veteran engineer or scientist. The description of the detailed characterization methodologies along with the precautions required during analysis are extremely important, as are the detailed description about the ultrasound assisted biodiesel production techniques, aviation biofuels and its characterization techniques, advance in algal biofuel techniques, pre-treatment of biomass for biofuel production, preparation and characterization of bio-catalyst, and various methods of optimization. The book offers a comparative study between the various liquid biofuels obtained from different methods of production and its engine performance and emission analysis so that one can get the utmost idea to find the better biofuel as an alternative fuel. Since the book covers almost all the field of liquid biofuel production techniques, it will provide advanced knowledge to the researcher for practical applications across the energy sector. A valuable reference for engineers, scientists, chemists, and students, this volume is applicable to many different fields, across many different industries, at all levels. It is a must-have for any library.
Book Synopsis New and Future Developments in Catalysis by : Lei Jin
Download or read book New and Future Developments in Catalysis written by Lei Jin and published by Elsevier Inc. Chapters. This book was released on 2013-07-17 with total page 34 pages. Available in PDF, EPUB and Kindle. Book excerpt:
The development of heterogeneous catalytic technologies for the selective conversion of lignocellulosic biomass to platform molecules such as 5-hydroxymethylfurfural (HMF) and 2,5-dihydroxymethylfurfural (DHMTHF) has been studied. Supported metal catalysts were used for the selective hydrogenation of HMF to DHMTHF. Small trace amounts of acid in the aqueous solution with HMF feed was found to play an important role in determining the selectivity for the hydrogenation of HMF to DHMTHF. DHMTHF, tetrahydrofuran (THF), gamma valerolactone (GVL), and other aprotic miscible organic solvents were mixed with water to form a monophasic co-solvent. These co solvents systems were found to be separation friendly solvents compared to dimethyl sulfoxide (DMSO) and other higher boiling organic solvents that are selective for HMF production. The monophasic co-solvents investigated were also selective for the production of HMF from fructose using Brønsted acid catalysts; additionally, an increase in the rate of reaction, compared to water, was observed. Fructose tautomerization favors the furanose form in the mixed solvent, relative to water alone, explaining at least part of the rate enhancement. The use of co-solvents and acid-functionalized ordered mesoporous silica catalysts show high selectivity for HMF from fructose. The synthesis to intercalate PVP on the catalyst surface was developed to achieve high selectivities previously achieved only with ionic liquids. The high concentration of pyrrolidone in the confined space of the pores favors the furanose tautomers which can be easily dehydrated to HMF. Thus, the reaction environment within the catalyst has been designed to favor the desired product. Solvent reactivity studies for homogenous base, homogenous Lewis acid, solid bases, and solid Lewis acids for glucose isomerization to fructose were conducted. The small addition of miscible organic solvent led to a drop of reactivity compared to that of pure water. However, with increasing GVL concentration, the reactivity increased as well. Benzene-bridged PMOs doped with Lewis acidic Sn sites were readily and rapidly synthesized. These thermally robust, hydrophobic materials catalyze the selective isomerization of glucose to fructose in co-solvent systems. Brønsted acid sites were incorporated and a bifunctional PMO was synthesized for tandem conversion of glucose to fructose and its dehydration to HMF.
Book Synopsis The Selective Production of Biomass Derived Chemicals Using Heterogeneous Catalysts by :
Download or read book The Selective Production of Biomass Derived Chemicals Using Heterogeneous Catalysts written by and published by . This book was released on 2016 with total page 320 pages. Available in PDF, EPUB and Kindle. Book excerpt: The development of heterogeneous catalytic technologies for the selective conversion of lignocellulosic biomass to platform molecules such as 5-hydroxymethylfurfural (HMF) and 2,5-dihydroxymethylfurfural (DHMTHF) has been studied. Supported metal catalysts were used for the selective hydrogenation of HMF to DHMTHF. Small trace amounts of acid in the aqueous solution with HMF feed was found to play an important role in determining the selectivity for the hydrogenation of HMF to DHMTHF. DHMTHF, tetrahydrofuran (THF), gamma valerolactone (GVL), and other aprotic miscible organic solvents were mixed with water to form a monophasic co-solvent. These co solvents systems were found to be separation friendly solvents compared to dimethyl sulfoxide (DMSO) and other higher boiling organic solvents that are selective for HMF production. The monophasic co-solvents investigated were also selective for the production of HMF from fructose using Brønsted acid catalysts; additionally, an increase in the rate of reaction, compared to water, was observed. Fructose tautomerization favors the furanose form in the mixed solvent, relative to water alone, explaining at least part of the rate enhancement. The use of co-solvents and acid-functionalized ordered mesoporous silica catalysts show high selectivity for HMF from fructose. The synthesis to intercalate PVP on the catalyst surface was developed to achieve high selectivities previously achieved only with ionic liquids. The high concentration of pyrrolidone in the confined space of the pores favors the furanose tautomers which can be easily dehydrated to HMF. Thus, the reaction environment within the catalyst has been designed to favor the desired product. Solvent reactivity studies for homogenous base, homogenous Lewis acid, solid bases, and solid Lewis acids for glucose isomerization to fructose were conducted. The small addition of miscible organic solvent led to a drop of reactivity compared to that of pure water. However, with increasing GVL concentration, the reactivity increased as well. Benzene-bridged PMOs doped with Lewis acidic Sn sites were readily and rapidly synthesized. These thermally robust, hydrophobic materials catalyze the selective isomerization of glucose to fructose in co-solvent systems. Brønsted acid sites were incorporated and a bifunctional PMO was synthesized for tandem conversion of glucose to fructose and its dehydration to HMF.
Advanced Functional Solid Catalysts for Biomass Valorization presents the basic concepts in catalysis (homogeneous, heterogeneous, and enzymatic) and the properties of various kinds of heterogeneous solid catalysts, including their structure, porosity, particle size, BET surface area, acid-base, and redox properties. Useful information about biorefineries, types of biomass feedstocks, their structures and properties as well as about several potential catalytic routes for biomass upgrading to useful fuels and chemicals is provided in this book. Importantly, this book covers the most recent developments toward functionalization of various solid catalysts, optimization of catalysts’ properties, developing cascade catalytic strategies, exploring reaction kinetics/mechanisms, and evaluating catalysts’ stability/reusability during biomass upgrading. Current challenges and opportunities for the future biorefineries as well as for the design of advanced functional solid catalysts are critically discussed. Describes catalysis as a promising technology for the development of eco-friendly and economically viable strategies for several important energy and environmental applications. Covers heterogeneous solid catalysts because of their versatile benefits in terms of catalysts’ synthesis, production cost, stability, and reusability as compared to homogeneous liquid catalysts. Provides promising strategies for the design of new catalytic materials, such as carbon materials, metal–organic frameworks, zeolites, and mesoporous silicas. Describes functional solid catalysts for developing one-pot cascade processes for efficient biomass valorization and other vital chemical transformations.
Book Synopsis Advanced Functional Solid Catalysts for Biomass Valorization by : Chaudhery Mustansar Hussain
Download or read book Advanced Functional Solid Catalysts for Biomass Valorization written by Chaudhery Mustansar Hussain and published by Elsevier. This book was released on 2020-05-29 with total page 276 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advanced Functional Solid Catalysts for Biomass Valorization presents the basic concepts in catalysis (homogeneous, heterogeneous, and enzymatic) and the properties of various kinds of heterogeneous solid catalysts, including their structure, porosity, particle size, BET surface area, acid-base, and redox properties. Useful information about biorefineries, types of biomass feedstocks, their structures and properties as well as about several potential catalytic routes for biomass upgrading to useful fuels and chemicals is provided in this book. Importantly, this book covers the most recent developments toward functionalization of various solid catalysts, optimization of catalysts’ properties, developing cascade catalytic strategies, exploring reaction kinetics/mechanisms, and evaluating catalysts’ stability/reusability during biomass upgrading. Current challenges and opportunities for the future biorefineries as well as for the design of advanced functional solid catalysts are critically discussed. Describes catalysis as a promising technology for the development of eco-friendly and economically viable strategies for several important energy and environmental applications. Covers heterogeneous solid catalysts because of their versatile benefits in terms of catalysts’ synthesis, production cost, stability, and reusability as compared to homogeneous liquid catalysts. Provides promising strategies for the design of new catalytic materials, such as carbon materials, metal–organic frameworks, zeolites, and mesoporous silicas. Describes functional solid catalysts for developing one-pot cascade processes for efficient biomass valorization and other vital chemical transformations.
The use of solid catalysts for the upgrade of renewable sources gives the opportunity to combine the two main cores of green chemistry, that is, on the one hand, the set-up of sustainable processes and, on the other, the use of biomass-derived materials. Solid catalysts have taken on a leading role in traditional petrochemical processes and could represent a key tool in new biorefinery-driven technologies. This book will cover topics related to the preparation and use of heterogeneous catalytic systems for the transformation of renewable sources, as well as of materials deriving from agro-industrial wastes and by-products. At the same time, the ever-increasing importance of bioproducts, due to the acceptance and request of consumers, makes the upgrade of biomass into chemicals and materials not only an environmental issue, but also an economical advantage.
Book Synopsis Solid Catalysts for the Upgrading of Renewable Sources by : Nicoletta Ravasio
Download or read book Solid Catalysts for the Upgrading of Renewable Sources written by Nicoletta Ravasio and published by MDPI. This book was released on 2019-03-26 with total page 226 pages. Available in PDF, EPUB and Kindle. Book excerpt: The use of solid catalysts for the upgrade of renewable sources gives the opportunity to combine the two main cores of green chemistry, that is, on the one hand, the set-up of sustainable processes and, on the other, the use of biomass-derived materials. Solid catalysts have taken on a leading role in traditional petrochemical processes and could represent a key tool in new biorefinery-driven technologies. This book will cover topics related to the preparation and use of heterogeneous catalytic systems for the transformation of renewable sources, as well as of materials deriving from agro-industrial wastes and by-products. At the same time, the ever-increasing importance of bioproducts, due to the acceptance and request of consumers, makes the upgrade of biomass into chemicals and materials not only an environmental issue, but also an economical advantage.
In Chapter 4, biomass-derived platform chemicals are used to produce bio-lubricant base oils. Our strategy involves coupling 12-tricosanone, obtained from bioderived fatty acids, with furfural, a C-5 species, obtained from hemicellulose, to form a highly branched bio-lubricant base oil. I show that the viscous properties of the final product are comparable to commercial petroleum-derived Group III and Group IV base oils.
Book Synopsis Homogeneous and Heterogeneous Catalysis for Biomass Upgrading to Platform Chemicals and End Products by : Angela M. Norton
Download or read book Homogeneous and Heterogeneous Catalysis for Biomass Upgrading to Platform Chemicals and End Products written by Angela M. Norton and published by . This book was released on 2020 with total page 180 pages. Available in PDF, EPUB and Kindle. Book excerpt: In Chapter 4, biomass-derived platform chemicals are used to produce bio-lubricant base oils. Our strategy involves coupling 12-tricosanone, obtained from bioderived fatty acids, with furfural, a C-5 species, obtained from hemicellulose, to form a highly branched bio-lubricant base oil. I show that the viscous properties of the final product are comparable to commercial petroleum-derived Group III and Group IV base oils.
