Carbon-carbon Bond Formation

Carbon-carbon Bond Formation

Author: Robert L. Augustine

Publisher: CRC Press

Published: 1979-04-01

Total Pages: 480

ISBN-13: 9780824767877

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Book Synopsis Carbon-carbon Bond Formation by : Robert L. Augustine

Download or read book Carbon-carbon Bond Formation written by Robert L. Augustine and published by CRC Press. This book was released on 1979-04-01 with total page 480 pages. Available in PDF, EPUB and Kindle. Book excerpt:


Carbon-Carbon ?-Bond Formation

Carbon-Carbon ?-Bond Formation

Author: G. Pattenden

Publisher: Elsevier

Published: 1992-09-08

Total Pages: 1209

ISBN-13: 008091246X

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Volume 3 covers carbon-to-carbon single bond forming reactions involving sp3, sp2 and sp carbon centers, but only those which do not involve additions to C-X &pgr;-bonds. The volume first compares and contrasts the alkylation reactions of all types of sp3 carbon nucleophiles and also covers vinyl and alkynyl carbanions. Following on from Volume 2, a separate section covers Friedel-Crafts alkylation reactions, which is complemented by discussions of polyene cyclizations and electrophilic transannular cyclizations in synthesis. Coupling reactions leading to &agr;-bond formation, and involving all types of combinations ofsp3, sp2 and sp carbon centers are next covered, including those reactions based on pinacol, acyloin and phenol oxidative coupling reactions, and also the Kolbe reaction. Rearrangement reactions, leading to carbon-to-carbon &agr;-bond formation, are often used in a clever manner in synthesis. The volume includes all those rearrangement reactions based on intermediate carbonium ions and carbanions, and also includes the benzil-benzilic acid and the Wolff rearrangements. The volume closes with coverage of carbonylation reactions, and the use of carbene insertion reactions into the C-H bond in synthesis.


Book Synopsis Carbon-Carbon ?-Bond Formation by : G. Pattenden

Download or read book Carbon-Carbon ?-Bond Formation written by G. Pattenden and published by Elsevier. This book was released on 1992-09-08 with total page 1209 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume 3 covers carbon-to-carbon single bond forming reactions involving sp3, sp2 and sp carbon centers, but only those which do not involve additions to C-X &pgr;-bonds. The volume first compares and contrasts the alkylation reactions of all types of sp3 carbon nucleophiles and also covers vinyl and alkynyl carbanions. Following on from Volume 2, a separate section covers Friedel-Crafts alkylation reactions, which is complemented by discussions of polyene cyclizations and electrophilic transannular cyclizations in synthesis. Coupling reactions leading to &agr;-bond formation, and involving all types of combinations ofsp3, sp2 and sp carbon centers are next covered, including those reactions based on pinacol, acyloin and phenol oxidative coupling reactions, and also the Kolbe reaction. Rearrangement reactions, leading to carbon-to-carbon &agr;-bond formation, are often used in a clever manner in synthesis. The volume includes all those rearrangement reactions based on intermediate carbonium ions and carbanions, and also includes the benzil-benzilic acid and the Wolff rearrangements. The volume closes with coverage of carbonylation reactions, and the use of carbene insertion reactions into the C-H bond in synthesis.


Modern Methods of Organic Synthesis South Asia Edition

Modern Methods of Organic Synthesis South Asia Edition

Author: W. Carruthers

Publisher: Cambridge University Press

Published: 2015-04-10

Total Pages: 506

ISBN-13: 1107567459

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Textbook on modern methods of organic synthesis.


Book Synopsis Modern Methods of Organic Synthesis South Asia Edition by : W. Carruthers

Download or read book Modern Methods of Organic Synthesis South Asia Edition written by W. Carruthers and published by Cambridge University Press. This book was released on 2015-04-10 with total page 506 pages. Available in PDF, EPUB and Kindle. Book excerpt: Textbook on modern methods of organic synthesis.


Carbon- carbon bond formation

Carbon- carbon bond formation

Author: Robert L. Augustine

Publisher:

Published: 1979

Total Pages:

ISBN-13:

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Book Synopsis Carbon- carbon bond formation by : Robert L. Augustine

Download or read book Carbon- carbon bond formation written by Robert L. Augustine and published by . This book was released on 1979 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:


Carbon-carbon bond formation

Carbon-carbon bond formation

Author: Robert L. Augustine

Publisher:

Published: 1979

Total Pages:

ISBN-13:

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Book Synopsis Carbon-carbon bond formation by : Robert L. Augustine

Download or read book Carbon-carbon bond formation written by Robert L. Augustine and published by . This book was released on 1979 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:


Radicals in Organic Synthesis

Radicals in Organic Synthesis

Author: Bernd Giese

Publisher: C R C Press Reprints

Published: 1986

Total Pages: 316

ISBN-13:

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Book Synopsis Radicals in Organic Synthesis by : Bernd Giese

Download or read book Radicals in Organic Synthesis written by Bernd Giese and published by C R C Press Reprints. This book was released on 1986 with total page 316 pages. Available in PDF, EPUB and Kindle. Book excerpt:


Metal Catalyzed Reductive C-C Bond Formation

Metal Catalyzed Reductive C-C Bond Formation

Author: Michael J. Krische

Publisher: Springer Science & Business Media

Published: 2007-07-20

Total Pages: 272

ISBN-13: 3540728783

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TheprototypicalcatalyticreductiveC-Cbondformations,theFischer-Tropsch reaction [1] and alkene hydroformylation [2], were discovered in 1922 and 1938, respectively [3,4]. These processes, which involve reductive coupling to carbon monoxide, have long been applied to the industrial manufacture of commodity chemicals [5]. Notably, alkene hydroformylation, also known as the oxo-synthesis, has emerged as the largest volume application of homo- neous metal catalysis, accounting for the production of over 7 million metric tons of aldehyde annually. Despite the impact of these prototypical reductive C-C bond formations, this ?eld of research lay fallow for several decades. Eventually, the increased availability of mild terminal reductants, in part- ular silanes, led to a renaissance in the area of catalytic reductive C-C bond formation.Forexample,the'rstcatalyticreductiveC-Ccouplingsbeyond- droformylation, which involve the hydrosilylative dimerization of conjugated dienes [6-12], appeared in 1969 - approximately 16 years after the ?rst - ported metal-catalyzed alkene hydrosilylation [13]. Following these seminal studies, the ?eld of catalytic reductive C-C bond formation underwent exp- sivegrowth,culminatingintheemergenceofanevergrowingbodyofresearch encompassing a powerful set of transformations. To our knowledge, no thematic volumes devoted solely to metal-catalyzed reductive C-C bond formationhave been assembled. For the ?rst time, in this issue of Topics in Current Chemistry,wepresent acompilation ofmonographs from several leaders in this burgeoning area of research. This collection of reviews serves to capture the diversity of catalytic reductive C-C couplings presently available and, in turn, the remarkable range of reactivity embodied by such transformations. There is no indication that this ?eld has reached its zenithanditisthehopeofthepresentauthorthatthisvolumewillfuelfurther progress.


Book Synopsis Metal Catalyzed Reductive C-C Bond Formation by : Michael J. Krische

Download or read book Metal Catalyzed Reductive C-C Bond Formation written by Michael J. Krische and published by Springer Science & Business Media. This book was released on 2007-07-20 with total page 272 pages. Available in PDF, EPUB and Kindle. Book excerpt: TheprototypicalcatalyticreductiveC-Cbondformations,theFischer-Tropsch reaction [1] and alkene hydroformylation [2], were discovered in 1922 and 1938, respectively [3,4]. These processes, which involve reductive coupling to carbon monoxide, have long been applied to the industrial manufacture of commodity chemicals [5]. Notably, alkene hydroformylation, also known as the oxo-synthesis, has emerged as the largest volume application of homo- neous metal catalysis, accounting for the production of over 7 million metric tons of aldehyde annually. Despite the impact of these prototypical reductive C-C bond formations, this ?eld of research lay fallow for several decades. Eventually, the increased availability of mild terminal reductants, in part- ular silanes, led to a renaissance in the area of catalytic reductive C-C bond formation.Forexample,the'rstcatalyticreductiveC-Ccouplingsbeyond- droformylation, which involve the hydrosilylative dimerization of conjugated dienes [6-12], appeared in 1969 - approximately 16 years after the ?rst - ported metal-catalyzed alkene hydrosilylation [13]. Following these seminal studies, the ?eld of catalytic reductive C-C bond formation underwent exp- sivegrowth,culminatingintheemergenceofanevergrowingbodyofresearch encompassing a powerful set of transformations. To our knowledge, no thematic volumes devoted solely to metal-catalyzed reductive C-C bond formationhave been assembled. For the ?rst time, in this issue of Topics in Current Chemistry,wepresent acompilation ofmonographs from several leaders in this burgeoning area of research. This collection of reviews serves to capture the diversity of catalytic reductive C-C couplings presently available and, in turn, the remarkable range of reactivity embodied by such transformations. There is no indication that this ?eld has reached its zenithanditisthehopeofthepresentauthorthatthisvolumewillfuelfurther progress.


Organometallics in Organic Synthesis

Organometallics in Organic Synthesis

Author: Armin de Meijere

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 321

ISBN-13: 3642731961

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More and more possible applications of organometallic compounds in organic synthesis have been uncovered and a growing number of scientists are attracted to this area of research. This book presents an state-of-the-art account of the successful application of main- and transition metal mediated syntheses. It will stimulate new ideas and initiate further research in all areas of this fascinating chemistry.


Book Synopsis Organometallics in Organic Synthesis by : Armin de Meijere

Download or read book Organometallics in Organic Synthesis written by Armin de Meijere and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 321 pages. Available in PDF, EPUB and Kindle. Book excerpt: More and more possible applications of organometallic compounds in organic synthesis have been uncovered and a growing number of scientists are attracted to this area of research. This book presents an state-of-the-art account of the successful application of main- and transition metal mediated syntheses. It will stimulate new ideas and initiate further research in all areas of this fascinating chemistry.


Applied Biocatalysis

Applied Biocatalysis

Author: John Whittall

Publisher: John Wiley & Sons

Published: 2020-08-21

Total Pages: 560

ISBN-13: 111948703X

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Provides clear and comprehensive coverage of recently developed applied biocatalysis for synthetic organic chemists with an emphasis to promote green chemistry in pharmaceutical and process chemistry This book aims to make biocatalysis more accessible to both academic and industrial synthetic organic chemists. It focuses on current topics within the applied industrial biocatalysis field and includes short but detailed experimental methods on timely novel biocatalytic transformations using new enzymes or new methodologies using known enzymes. The book also features reactions that are “expanding and making the enzyme toolbox available to chemists”—providing readers with comprehensive methodology and detailed key sourcing information of a wide range of enzymes. Chapters in Applied Biocatalysis: The Chemist’s Enzyme Toolkit are organized by reaction type and feature a short introductory section describing the current state of the art for each example. Much of the book focuses on processes for which the enzymes are readily available so that organic chemists can synthesize appropriate quantities of chemicals with available materials in a standard chemical laboratory. Advanced methods are included to present examples of new enzymes that might encourage collaboration with suppliers or academic groups and that will educate chemists of rapidly expanding future possibilities. Focuses on current topics within the applied industrial biocatalysis field Offers experimental methods on novel biocatalytic transformations using new enzymes or new methodology using known enzymes Covers the hot topics of enzyme and chemoenzymatic cascades and biocatalysis in flow Edited by noted experts from both academia and industry with years of experience in the field of biocatalysis—particularly, the industrial applications of enzymes Written for synthetic organic chemists working in all industries but especially the pharmaceutical industry and for those in academia with an eye for biocatalysis, Applied Biocatalysis: The Chemist’s Enzyme Toolkit will also benefit academic groups in chemistry and related sciences that are using enzymes for synthetic purposes, as well as those working in the area of enzymology and molecular biology.


Book Synopsis Applied Biocatalysis by : John Whittall

Download or read book Applied Biocatalysis written by John Whittall and published by John Wiley & Sons. This book was released on 2020-08-21 with total page 560 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides clear and comprehensive coverage of recently developed applied biocatalysis for synthetic organic chemists with an emphasis to promote green chemistry in pharmaceutical and process chemistry This book aims to make biocatalysis more accessible to both academic and industrial synthetic organic chemists. It focuses on current topics within the applied industrial biocatalysis field and includes short but detailed experimental methods on timely novel biocatalytic transformations using new enzymes or new methodologies using known enzymes. The book also features reactions that are “expanding and making the enzyme toolbox available to chemists”—providing readers with comprehensive methodology and detailed key sourcing information of a wide range of enzymes. Chapters in Applied Biocatalysis: The Chemist’s Enzyme Toolkit are organized by reaction type and feature a short introductory section describing the current state of the art for each example. Much of the book focuses on processes for which the enzymes are readily available so that organic chemists can synthesize appropriate quantities of chemicals with available materials in a standard chemical laboratory. Advanced methods are included to present examples of new enzymes that might encourage collaboration with suppliers or academic groups and that will educate chemists of rapidly expanding future possibilities. Focuses on current topics within the applied industrial biocatalysis field Offers experimental methods on novel biocatalytic transformations using new enzymes or new methodology using known enzymes Covers the hot topics of enzyme and chemoenzymatic cascades and biocatalysis in flow Edited by noted experts from both academia and industry with years of experience in the field of biocatalysis—particularly, the industrial applications of enzymes Written for synthetic organic chemists working in all industries but especially the pharmaceutical industry and for those in academia with an eye for biocatalysis, Applied Biocatalysis: The Chemist’s Enzyme Toolkit will also benefit academic groups in chemistry and related sciences that are using enzymes for synthetic purposes, as well as those working in the area of enzymology and molecular biology.


The Chemistry of the Metal Carbon Bond, Volume 3

The Chemistry of the Metal Carbon Bond, Volume 3

Author: Frank R. Hartley

Publisher: Wiley

Published: 1985

Total Pages: 512

ISBN-13: 9780471905578

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This is the third volume in the series edited by Frank Hartley on The Chemistry of the Metal Carbon Bond. The series is concerned with organometallic compounds from the point of view of the carbon end of the bond and is, therefore, relevant to Organic Chemists. This particular volume is concerned with Carbon-Carbon bonds and their formation using organometallic compounds.


Book Synopsis The Chemistry of the Metal Carbon Bond, Volume 3 by : Frank R. Hartley

Download or read book The Chemistry of the Metal Carbon Bond, Volume 3 written by Frank R. Hartley and published by Wiley. This book was released on 1985 with total page 512 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is the third volume in the series edited by Frank Hartley on The Chemistry of the Metal Carbon Bond. The series is concerned with organometallic compounds from the point of view of the carbon end of the bond and is, therefore, relevant to Organic Chemists. This particular volume is concerned with Carbon-Carbon bonds and their formation using organometallic compounds.