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Chemical Physics of Intercalation

Author: A.P. Legrand

Publisher: Springer Science & Business Media

Published: 2013-12-11

Total Pages: 503

ISBN-13: 1475796498

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Conjugated polymers suoh as polyaoetylene (CH)x polyphenylene (C6H4)x' poly thiophene (C4H2S)x' etc., which are insulators in their pristine state, can be brought to the metallic state after "doping" with ohemioal speoies whioh oan be either eleotron donors or I aoceptors. . This doping prooess involves a oharge transfer between the dopant moleoule and the polymer ohain whioh are then supposed to be spatially olose to each other. It follows that the meohanism of doping must be oonsidered as an aotual interoalation process, which will greatly affeot the struotural oharacteristios of the starting material, as well as its morphology, as has been observed during the 2 intercalation of graphite and layered compounds . In parallel with these modifioations, the band struoture of the system changes yielding a new set of eleotronio properties. It is evident therefore that the struotural and eleotronio properties are intimately related, and must be studied simultaneously in the same system to give reliable information. A great number of studies have been devoted to the structural and electronic properties of conjugated polymers after a chemical or 2 electrochemical doping process . Most of these concern the properties of the system for a given dopant concentration. With this approach a universal pioture of the polymer/dopant system is very diffioult to obtain, as a comparison between different experiments is very hazardous. On the other hand, only a small number of measurements have been performed during the continuous electroohemioal doping of various polymers.

Book Synopsis Chemical Physics of Intercalation by : A.P. Legrand

Download or read book Chemical Physics of Intercalation written by A.P. Legrand and published by Springer Science & Business Media. This book was released on 2013-12-11 with total page 503 pages. Available in PDF, EPUB and Kindle. Book excerpt: Conjugated polymers suoh as polyaoetylene (CH)x polyphenylene (C6H4)x' poly thiophene (C4H2S)x' etc., which are insulators in their pristine state, can be brought to the metallic state after "doping" with ohemioal speoies whioh oan be either eleotron donors or I aoceptors. . This doping prooess involves a oharge transfer between the dopant moleoule and the polymer ohain whioh are then supposed to be spatially olose to each other. It follows that the meohanism of doping must be oonsidered as an aotual interoalation process, which will greatly affeot the struotural oharacteristios of the starting material, as well as its morphology, as has been observed during the 2 intercalation of graphite and layered compounds . In parallel with these modifioations, the band struoture of the system changes yielding a new set of eleotronio properties. It is evident therefore that the struotural and eleotronio properties are intimately related, and must be studied simultaneously in the same system to give reliable information. A great number of studies have been devoted to the structural and electronic properties of conjugated polymers after a chemical or 2 electrochemical doping process . Most of these concern the properties of the system for a given dopant concentration. With this approach a universal pioture of the polymer/dopant system is very diffioult to obtain, as a comparison between different experiments is very hazardous. On the other hand, only a small number of measurements have been performed during the continuous electroohemioal doping of various polymers.

Chemical Physics of Intercalation II

Author: Patrick Bernier

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 402

ISBN-13: 146152850X

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This volume provides a record of the second ASI on the subject "Chemical Physics of Intercalation", which was patterned after its highly successful July 1987 predecessor. A growing community of chemists, physicists and materials scientists has come to appreciate the utility of extending the intercalation concept to generic guest-host compounds and solid solutions. The unifying themes are the complex phase equilibria which result from the competition between repulsive and attractive interactions between and within the guest and host substructures, the tunability of properties by control of guest concentration and superlattice periodicity, and the broad spectrum of potential applications which these materials may provide. The success of this initiative may be judged by noting the enlarged scope of materials covered in this volume as compared to its predecessor. The present volume covers the spectrum from 3-dimensional oxides, 2-dimensional classical layer intercalates,- dimensional doped polymers and zero-dimensional doped fullerene lattices. Hybrid systems such as polymers in layer hosts and nonporous hosts are also treated. Several chapters provide global unifying viewpoints by focussing on sold state chemical aspects, transport and optical properties, the occurrence of superconductivity, etc.

Book Synopsis Chemical Physics of Intercalation II by : Patrick Bernier

Download or read book Chemical Physics of Intercalation II written by Patrick Bernier and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 402 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume provides a record of the second ASI on the subject "Chemical Physics of Intercalation", which was patterned after its highly successful July 1987 predecessor. A growing community of chemists, physicists and materials scientists has come to appreciate the utility of extending the intercalation concept to generic guest-host compounds and solid solutions. The unifying themes are the complex phase equilibria which result from the competition between repulsive and attractive interactions between and within the guest and host substructures, the tunability of properties by control of guest concentration and superlattice periodicity, and the broad spectrum of potential applications which these materials may provide. The success of this initiative may be judged by noting the enlarged scope of materials covered in this volume as compared to its predecessor. The present volume covers the spectrum from 3-dimensional oxides, 2-dimensional classical layer intercalates,- dimensional doped polymers and zero-dimensional doped fullerene lattices. Hybrid systems such as polymers in layer hosts and nonporous hosts are also treated. Several chapters provide global unifying viewpoints by focussing on sold state chemical aspects, transport and optical properties, the occurrence of superconductivity, etc.

Chemical Physics of Intercalation

Author:

Publisher:

Published: 19??

Total Pages:

ISBN-13:

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Book Synopsis Chemical Physics of Intercalation by :

Download or read book Chemical Physics of Intercalation written by and published by . This book was released on 19?? with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Chemical Physics of Intercalation (Volume 172).

Author: AP Legrand (Ed)

Publisher:

Published: 1987

Total Pages:

ISBN-13:

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Book Synopsis Chemical Physics of Intercalation (Volume 172). by : AP Legrand (Ed)

Download or read book Chemical Physics of Intercalation (Volume 172). written by AP Legrand (Ed) and published by . This book was released on 1987 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Intercalation Chemistry

Author: Stanley M Whittingha

Publisher: Elsevier

Published: 2012-12-02

Total Pages: 614

ISBN-13: 0323140408

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Intercalation Chemistry introduces the specialist reader to the breadth of intercalation chemistry and the newcomer to the diverse research opportunities and challenges available in synthetic and reaction chemistry and also in the controlled modification of physical properties. Topics covered range from graphite chemistry to sheet silicate intercalates, diffusion and shape-selective catalysis in zeolites, organic and organometallic intercalation compounds of the transition metal dichalcogenides, and solvated intercalation compounds of layered chalcogenide and oxide bronzes. This book is comprised of 18 chapters and begins with an introduction to intercalation chemistry. The discussions that follow focus on the intercalation chemistry of graphite and of complex oxides with both two (clays and acid phosphates)- and three (zeolites)-dimensional structures, along with organic conversions that have been discovered using essentially smectite (i.e., montmorillonite- and hectorite-based) intercalates. The next chapters focus on ß-aluminas, acid salts of tetravalent metals with layered structure, and layered chalcogenides and halides with simple and hydrated cations as well as organic and organometallic ions. The book also considers the chemistry, thermodynamics, and applications of intermetallic compounds that incorporate hydrogen, intercalation in the context of biological systems, crystallographic shear structures, and intercalation reactions of oxides and chalcogenides of vanadium, molybdenum, and tungsten. The final chapter touches on the physical properties of some intercalation compounds of the dichalcogenides. This book is intended for researchers in the various materials science disciplines.

Book Synopsis Intercalation Chemistry by : Stanley M Whittingha

Download or read book Intercalation Chemistry written by Stanley M Whittingha and published by Elsevier. This book was released on 2012-12-02 with total page 614 pages. Available in PDF, EPUB and Kindle. Book excerpt: Intercalation Chemistry introduces the specialist reader to the breadth of intercalation chemistry and the newcomer to the diverse research opportunities and challenges available in synthetic and reaction chemistry and also in the controlled modification of physical properties. Topics covered range from graphite chemistry to sheet silicate intercalates, diffusion and shape-selective catalysis in zeolites, organic and organometallic intercalation compounds of the transition metal dichalcogenides, and solvated intercalation compounds of layered chalcogenide and oxide bronzes. This book is comprised of 18 chapters and begins with an introduction to intercalation chemistry. The discussions that follow focus on the intercalation chemistry of graphite and of complex oxides with both two (clays and acid phosphates)- and three (zeolites)-dimensional structures, along with organic conversions that have been discovered using essentially smectite (i.e., montmorillonite- and hectorite-based) intercalates. The next chapters focus on ß-aluminas, acid salts of tetravalent metals with layered structure, and layered chalcogenides and halides with simple and hydrated cations as well as organic and organometallic ions. The book also considers the chemistry, thermodynamics, and applications of intermetallic compounds that incorporate hydrogen, intercalation in the context of biological systems, crystallographic shear structures, and intercalation reactions of oxides and chalcogenides of vanadium, molybdenum, and tungsten. The final chapter touches on the physical properties of some intercalation compounds of the dichalcogenides. This book is intended for researchers in the various materials science disciplines.

Intercalated Layered Materials

Author: F.A. Lévy

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 580

ISBN-13: 940099415X

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Materials with layered structures remain an extensively investigated subject in current physics and chemistry. Most of the promising technological applications however deal with intercalation compounds of layered materials. Graphite intercalation compounds have now been known for a long time. Intercalation in transition metal dichalcogenides, on the other hand, has been investigated only recently. The amount of information on intercalated layered materials has increased far beyond the original concept for this volume in the series Physics and Chemistry of Materials with Layered Structures. The large size of this volume also indicates how important this field of research will be, not only in basic science, but also in industrial and energy applications. In this volume, two classes of materials are included, generally investigated by different scientists. Graphite intercalates and intercalates of other inorganic com pounds actually constitute separate classes of materials. However, the similarity between the intercalation techniques and some intercalation processes does not justify this separation, and accounts for the inclusion of both classes in this volume. The first part of the volume deals with intercalation processes and intercalates of transition metal dichalcogenides. Several chapters include connected topics necessary to give a good introduction or comprehensive review of these types of materials. Organic as well as inorganic intercalation compounds are treated. The second part includes contributions concerning graphite intercalates. It should be noted that graphite intercalation compounds have already been mentioned in Volumes I and V.

Book Synopsis Intercalated Layered Materials by : F.A. Lévy

Download or read book Intercalated Layered Materials written by F.A. Lévy and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 580 pages. Available in PDF, EPUB and Kindle. Book excerpt: Materials with layered structures remain an extensively investigated subject in current physics and chemistry. Most of the promising technological applications however deal with intercalation compounds of layered materials. Graphite intercalation compounds have now been known for a long time. Intercalation in transition metal dichalcogenides, on the other hand, has been investigated only recently. The amount of information on intercalated layered materials has increased far beyond the original concept for this volume in the series Physics and Chemistry of Materials with Layered Structures. The large size of this volume also indicates how important this field of research will be, not only in basic science, but also in industrial and energy applications. In this volume, two classes of materials are included, generally investigated by different scientists. Graphite intercalates and intercalates of other inorganic com pounds actually constitute separate classes of materials. However, the similarity between the intercalation techniques and some intercalation processes does not justify this separation, and accounts for the inclusion of both classes in this volume. The first part of the volume deals with intercalation processes and intercalates of transition metal dichalcogenides. Several chapters include connected topics necessary to give a good introduction or comprehensive review of these types of materials. Organic as well as inorganic intercalation compounds are treated. The second part includes contributions concerning graphite intercalates. It should be noted that graphite intercalation compounds have already been mentioned in Volumes I and V.

Progress in Intercalation Research

Author: W. Müller-Warmuth

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 525

ISBN-13: 9401108900

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The combination of solid materials of different structural dimensionality with atomic or molecular guest species via intercalation processes represents a unique and widely variable low temperature synthesis strategy for the design of solids with particular composition, structure and physical properties. In the last decade this field has experienced a rapid development and represents now an established specific domain of solid state research and materials science. Substantial progress has been made with respect to an understanding of the complex relationship between structure, bonding, physical properties and chemical reactivity since the first volume on the subject appeared in this series in 1979 (Intercalated Layered Materials, F. Levy, ed.). The purpose of this volume is to present a survey on progress and per spectives based on the treatment of a series of major areas of activities in this field. By the very nature of its subject this monograph has an interdisciplinary character and addresses itself to chemists, physicists and materials scien tists interested in intercalation research and related aspects such as design and characterization of complex materials, low temperature synthesis, solid state reaction mechanisms, electronic/ionic conductivity, control of electronic properties of solids with different structural dimensionality and application of intercalation systems. Several chapters have been devoted to specific groups of host lattices.

Book Synopsis Progress in Intercalation Research by : W. Müller-Warmuth

Download or read book Progress in Intercalation Research written by W. Müller-Warmuth and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 525 pages. Available in PDF, EPUB and Kindle. Book excerpt: The combination of solid materials of different structural dimensionality with atomic or molecular guest species via intercalation processes represents a unique and widely variable low temperature synthesis strategy for the design of solids with particular composition, structure and physical properties. In the last decade this field has experienced a rapid development and represents now an established specific domain of solid state research and materials science. Substantial progress has been made with respect to an understanding of the complex relationship between structure, bonding, physical properties and chemical reactivity since the first volume on the subject appeared in this series in 1979 (Intercalated Layered Materials, F. Levy, ed.). The purpose of this volume is to present a survey on progress and per spectives based on the treatment of a series of major areas of activities in this field. By the very nature of its subject this monograph has an interdisciplinary character and addresses itself to chemists, physicists and materials scien tists interested in intercalation research and related aspects such as design and characterization of complex materials, low temperature synthesis, solid state reaction mechanisms, electronic/ionic conductivity, control of electronic properties of solids with different structural dimensionality and application of intercalation systems. Several chapters have been devoted to specific groups of host lattices.

New Trends in Intercalation Compounds for Energy Storage

Author: Christian Julien

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 655

ISBN-13: 9401003890

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Recent advances in electrochemistry and materials science have opened the way to the evolution of entirely new types of energy storage systems: rechargeable lithium-ion batteries, electrochroms, hydrogen containers, etc., all of which have greatly improved electrical performance and other desirable characteristics. This book encompasses all the disciplines linked in the progress from fundamentals to applications, from description and modelling of different materials to technological use, from general diagnostics to methods related to technological control and operation of intercalation compounds. Designing devices with higher specific energy and power will require a more profound understanding of material properties and performance. This book covers the status of materials and advanced activities based on the development of new substances for energy storage.

Book Synopsis New Trends in Intercalation Compounds for Energy Storage by : Christian Julien

Download or read book New Trends in Intercalation Compounds for Energy Storage written by Christian Julien and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 655 pages. Available in PDF, EPUB and Kindle. Book excerpt: Recent advances in electrochemistry and materials science have opened the way to the evolution of entirely new types of energy storage systems: rechargeable lithium-ion batteries, electrochroms, hydrogen containers, etc., all of which have greatly improved electrical performance and other desirable characteristics. This book encompasses all the disciplines linked in the progress from fundamentals to applications, from description and modelling of different materials to technological use, from general diagnostics to methods related to technological control and operation of intercalation compounds. Designing devices with higher specific energy and power will require a more profound understanding of material properties and performance. This book covers the status of materials and advanced activities based on the development of new substances for energy storage.

Lithium Intercalation in Bilayer Graphene Devices

Author: Matthias Kühne

Publisher: Springer

Published: 2018-11-27

Total Pages: 116

ISBN-13: 3030023664

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This book reports on the successful implementation of an innovative, miniaturized galvanic cell that offers unprecedented control over and access to ionic transport. It represents a milestone in fundamental studies on the diffusive transport of lithium ions between two atomically thin layers of carbon (graphene), a highly relevant aspect in electrodes for energy and mass storage in the context of batteries. Further, it is a beautiful example of how interdisciplinary work that combines expertise from two very distinct fields can significantly advance science. Machinery and tools common in the study of low-dimensional systems in condensed matter physics are combined with methods routinely employed in electrochemistry to enable truly unique and powerful experiments. The method developed here can easily be generalized and extended to other layered materials as well as other ionic species. Not only the method but also the outcome of its application to Li diffusion and intercalation in bilayer graphene is remarkable. A record chemical diffusion coefficient is demonstrated, exceeding even the diffusion of sodium chloride in water and surpassing any reported value of ion diffusion in single-phase mixed conducting materials. This finding may be indicative of the exceptional properties yet to be discovered in nanoscale derivatives of bulk insertion compounds.

Book Synopsis Lithium Intercalation in Bilayer Graphene Devices by : Matthias Kühne

Download or read book Lithium Intercalation in Bilayer Graphene Devices written by Matthias Kühne and published by Springer. This book was released on 2018-11-27 with total page 116 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book reports on the successful implementation of an innovative, miniaturized galvanic cell that offers unprecedented control over and access to ionic transport. It represents a milestone in fundamental studies on the diffusive transport of lithium ions between two atomically thin layers of carbon (graphene), a highly relevant aspect in electrodes for energy and mass storage in the context of batteries. Further, it is a beautiful example of how interdisciplinary work that combines expertise from two very distinct fields can significantly advance science. Machinery and tools common in the study of low-dimensional systems in condensed matter physics are combined with methods routinely employed in electrochemistry to enable truly unique and powerful experiments. The method developed here can easily be generalized and extended to other layered materials as well as other ionic species. Not only the method but also the outcome of its application to Li diffusion and intercalation in bilayer graphene is remarkable. A record chemical diffusion coefficient is demonstrated, exceeding even the diffusion of sodium chloride in water and surpassing any reported value of ion diffusion in single-phase mixed conducting materials. This finding may be indicative of the exceptional properties yet to be discovered in nanoscale derivatives of bulk insertion compounds.

Intercalation Compounds

Author: D. Tchoubar

Publisher: Trans Tech Publications Ltd

Published: 1992-01-01

Total Pages: 880

ISBN-13: 3035704643

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The volumes center on the following themes:

Book Synopsis Intercalation Compounds by : D. Tchoubar

Download or read book Intercalation Compounds written by D. Tchoubar and published by Trans Tech Publications Ltd. This book was released on 1992-01-01 with total page 880 pages. Available in PDF, EPUB and Kindle. Book excerpt: The volumes center on the following themes: