Deactivation And Regeneration Of Zeolite Catalysts

Deactivation And Regeneration Of Zeolite Catalysts

Author: Guisnet Michel

Publisher: World Scientific Publishing Company

Published: 2011-02-21

Total Pages: 360

ISBN-13: 1911299530

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In chemical processes, the progressive deactivation of solid catalysts is a major economic concern and mastering their stability has become as essential as controlling their activity and selectivity. For these reasons, there is a strong motivation to understand the mechanisms leading to any loss in activity and/or selectivity and to find out the efficient preventive measures and regenerative solutions that open the way towards cheaper and cleaner processes. This book covers the fundamental and applied aspects of solid catalyst deactivation in a comprehensive way and encompasses the state of the art in the field of reactions catalyzed by zeolites. This particular choice is justified by the widespread use of molecular sieves in refining, petrochemicals and organic chemicals synthesis processes, by the large variety in the nature of their active sites (acid, base, acid-base, redox, bifunctional) and especially by their peculiar features, in terms of crystallinity, structural order and textural properties, which make them ideal models for heterogeneous catalysis. The aim of this book is to be a critical review in the field of zeolite deactivation and regeneration by collecting contributions from experts in the field which describe the factors, explain the techniques to study the causes and suggest methods to prevent (or limit) catalyst deactivation. At the same time, a selection of commercial processes and exemplar cases provides the reader with theoretical insights and practical hints on the deactivation mechanisms and draws attention to the key role played by the loss of activity on process design and industrial practice./a


Book Synopsis Deactivation And Regeneration Of Zeolite Catalysts by : Guisnet Michel

Download or read book Deactivation And Regeneration Of Zeolite Catalysts written by Guisnet Michel and published by World Scientific Publishing Company. This book was released on 2011-02-21 with total page 360 pages. Available in PDF, EPUB and Kindle. Book excerpt: In chemical processes, the progressive deactivation of solid catalysts is a major economic concern and mastering their stability has become as essential as controlling their activity and selectivity. For these reasons, there is a strong motivation to understand the mechanisms leading to any loss in activity and/or selectivity and to find out the efficient preventive measures and regenerative solutions that open the way towards cheaper and cleaner processes. This book covers the fundamental and applied aspects of solid catalyst deactivation in a comprehensive way and encompasses the state of the art in the field of reactions catalyzed by zeolites. This particular choice is justified by the widespread use of molecular sieves in refining, petrochemicals and organic chemicals synthesis processes, by the large variety in the nature of their active sites (acid, base, acid-base, redox, bifunctional) and especially by their peculiar features, in terms of crystallinity, structural order and textural properties, which make them ideal models for heterogeneous catalysis. The aim of this book is to be a critical review in the field of zeolite deactivation and regeneration by collecting contributions from experts in the field which describe the factors, explain the techniques to study the causes and suggest methods to prevent (or limit) catalyst deactivation. At the same time, a selection of commercial processes and exemplar cases provides the reader with theoretical insights and practical hints on the deactivation mechanisms and draws attention to the key role played by the loss of activity on process design and industrial practice./a

Deactivation and Regeneration of Zeolite Catalysts

Deactivation and Regeneration of Zeolite Catalysts

Author: M. Guisnet

Publisher: World Scientific

Published: 2011

Total Pages: 359

ISBN-13: 1848166370

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In chemical processes, the progressive deactivation of solid catalysts is a major economic concern and mastering their stability has become as essential as controlling their activity and selectivity. For these reasons, there is a strong motivation to understand the mechanisms leading to any loss in activity and/or selectivity and to find out the efficient preventive measures and regenerative solutions that open the way towards cheaper and cleaner processes. This book covers in a comprehensive way both the fundamental and applied aspects of solid catalyst deactivation and encompasses the state-of-the-art in the field of reactions catalyzed by zeolites. This particular choice is justified by the widespread use of molecular sieves in refining, petrochemicals and organic chemicals synthesis processes, by the large variety in the nature of their active sites (acid, base, acid-base, redox, bifunctional) and especially by their peculiar features, in terms of crystallinity, structural order and textural properties, which make them ideal models for heterogeneous catalysis. The aim of this book is to be a critical review in the field of zeolite deactivation and regeneration, by collecting a series of contributions by experts in the field which describe the factors, explain the techniques to study the causes and suggest methods to prevent (or limit) catalyst deactivation. At the same time, an anthology of commercial processes and exemplar cases provides the reader with theoretical insights and practical hints on the deactivation mechanisms and draws attention to the key role played by the loss of activity on process design and industrial practice.


Book Synopsis Deactivation and Regeneration of Zeolite Catalysts by : M. Guisnet

Download or read book Deactivation and Regeneration of Zeolite Catalysts written by M. Guisnet and published by World Scientific. This book was released on 2011 with total page 359 pages. Available in PDF, EPUB and Kindle. Book excerpt: In chemical processes, the progressive deactivation of solid catalysts is a major economic concern and mastering their stability has become as essential as controlling their activity and selectivity. For these reasons, there is a strong motivation to understand the mechanisms leading to any loss in activity and/or selectivity and to find out the efficient preventive measures and regenerative solutions that open the way towards cheaper and cleaner processes. This book covers in a comprehensive way both the fundamental and applied aspects of solid catalyst deactivation and encompasses the state-of-the-art in the field of reactions catalyzed by zeolites. This particular choice is justified by the widespread use of molecular sieves in refining, petrochemicals and organic chemicals synthesis processes, by the large variety in the nature of their active sites (acid, base, acid-base, redox, bifunctional) and especially by their peculiar features, in terms of crystallinity, structural order and textural properties, which make them ideal models for heterogeneous catalysis. The aim of this book is to be a critical review in the field of zeolite deactivation and regeneration, by collecting a series of contributions by experts in the field which describe the factors, explain the techniques to study the causes and suggest methods to prevent (or limit) catalyst deactivation. At the same time, an anthology of commercial processes and exemplar cases provides the reader with theoretical insights and practical hints on the deactivation mechanisms and draws attention to the key role played by the loss of activity on process design and industrial practice.

Deactivation and Regeneration of Zeolite Catalysts

Deactivation and Regeneration of Zeolite Catalysts

Author: John A. Horsley

Publisher:

Published: 1991

Total Pages: 191

ISBN-13:

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Book Synopsis Deactivation and Regeneration of Zeolite Catalysts by : John A. Horsley

Download or read book Deactivation and Regeneration of Zeolite Catalysts written by John A. Horsley and published by . This book was released on 1991 with total page 191 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Zeolites for Cleaner Technologies

Zeolites for Cleaner Technologies

Author: Michel Guisnet

Publisher: World Scientific

Published: 2002-09-19

Total Pages: 388

ISBN-13: 178326117X

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This book, written and edited by leading authorities from academia and industrial groups, covers both preventive- and curative-zeolite-based technologies in the field of chemical processing. The opening chapter presents the state of the art in zeolite science. The two subsequent chapters summarize the chemistries involved in the processes and the constraints imposed on the catalyst/adsorbent. Three major areas are covered: oil refining, petrochemicals and fine chemicals. A chapter on the (curative) use of zeolites in pollution abatement completes this overview. In the area of oil refining, a general lecture sets the scene for present and future challenges. It is followed by in-depth case studies involving FCC, hydrocracking and light naphtha isomerization. Also, an entire chapter is devoted to the often-overlooked subject of base oils. In the area of petrochemicals, the processing of aromatics and olefins is described and special attention is paid to the synergy between catalysis and separation on molecular sieves. Contents:Introduction to Zeolite Science and Technology (M Guisnet & J-P Gilson)The Chemistry of Catalytic Processes (A Corma & A Martínez)Preparation of Zeolite Catalysts (T G Roberie et al.)Refining Processes: Setting the Scene (R H Jensen)Advances in Fluid Catalytic Cracking (E T Habib et al.)Hydrocracking (J A R Van Veen)C4-C6 Alkane Isomerisation (F Schmidt & E Köhler)Base Oil Production and Processing (M Daage)Para-Xylene ManufacturingCatalytic Reactions and Processes (F Alario & M Guisnet)Separation of Paraxylene by Adsorption (A Méthivier)Aromatic Alkylation: Towards Cleaner Processes (J S Beck et al.)Methanol to Olefins (MTO) and Beyond (P Barger)Zeolite Effects on Catalytic Transformations of Fine Chemicals (D E De Vos & P A Jacobs)Functionalization of Aromatics over Zeolite Catalysts (P Marion et al.)Zeolites and ‘Non-Zeolite’ Molecular Sieves in the Synthesis of Fragrances and Flavors (W F Hoelderich & M C Laufer)Pollution Abatment Using Zeolites: State of the Art and Further Needs (G Delahay & B Coq) Readership: Undergraduates, graduate students, academics and researchers in catalyst chemistry. Reviews:“Chapter authors have provided a teaching text that gives excellent introductory chapters to zeolites, and to the nature and significance of the processes that they can catalyse … This excellent book should be required reading for all scientists who have an interest in improving the environment.”Chemistry & Industry


Book Synopsis Zeolites for Cleaner Technologies by : Michel Guisnet

Download or read book Zeolites for Cleaner Technologies written by Michel Guisnet and published by World Scientific. This book was released on 2002-09-19 with total page 388 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book, written and edited by leading authorities from academia and industrial groups, covers both preventive- and curative-zeolite-based technologies in the field of chemical processing. The opening chapter presents the state of the art in zeolite science. The two subsequent chapters summarize the chemistries involved in the processes and the constraints imposed on the catalyst/adsorbent. Three major areas are covered: oil refining, petrochemicals and fine chemicals. A chapter on the (curative) use of zeolites in pollution abatement completes this overview. In the area of oil refining, a general lecture sets the scene for present and future challenges. It is followed by in-depth case studies involving FCC, hydrocracking and light naphtha isomerization. Also, an entire chapter is devoted to the often-overlooked subject of base oils. In the area of petrochemicals, the processing of aromatics and olefins is described and special attention is paid to the synergy between catalysis and separation on molecular sieves. Contents:Introduction to Zeolite Science and Technology (M Guisnet & J-P Gilson)The Chemistry of Catalytic Processes (A Corma & A Martínez)Preparation of Zeolite Catalysts (T G Roberie et al.)Refining Processes: Setting the Scene (R H Jensen)Advances in Fluid Catalytic Cracking (E T Habib et al.)Hydrocracking (J A R Van Veen)C4-C6 Alkane Isomerisation (F Schmidt & E Köhler)Base Oil Production and Processing (M Daage)Para-Xylene ManufacturingCatalytic Reactions and Processes (F Alario & M Guisnet)Separation of Paraxylene by Adsorption (A Méthivier)Aromatic Alkylation: Towards Cleaner Processes (J S Beck et al.)Methanol to Olefins (MTO) and Beyond (P Barger)Zeolite Effects on Catalytic Transformations of Fine Chemicals (D E De Vos & P A Jacobs)Functionalization of Aromatics over Zeolite Catalysts (P Marion et al.)Zeolites and ‘Non-Zeolite’ Molecular Sieves in the Synthesis of Fragrances and Flavors (W F Hoelderich & M C Laufer)Pollution Abatment Using Zeolites: State of the Art and Further Needs (G Delahay & B Coq) Readership: Undergraduates, graduate students, academics and researchers in catalyst chemistry. Reviews:“Chapter authors have provided a teaching text that gives excellent introductory chapters to zeolites, and to the nature and significance of the processes that they can catalyse … This excellent book should be required reading for all scientists who have an interest in improving the environment.”Chemistry & Industry

Catalysts Deactivation, Poisoning and Regeneration

Catalysts Deactivation, Poisoning and Regeneration

Author: Luciana Lisi

Publisher: MDPI

Published: 2019-10-01

Total Pages: 254

ISBN-13: 3039215469

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Catalyst lifetime represents one of the most crucial economic aspects in industrial catalytic processes, due to costly shutdowns, catalyst replacements, and proper disposal of spent materials. Not surprisingly, there is considerable motivation to understand and treat catalyst deactivation, poisoning, and regeneration, which causes this research topic to continue to grow. The complexity of catalyst poisoning obviously increases along with the increasing use of biomass/waste-derived/residual feedstocks and with requirements for cleaner and novel sustainable processes. This book collects 15 research papers providing insights into several scientific and technical aspects of catalyst poisoning and deactivation, proposing more tolerant catalyst formulations, and exploring possible regeneration strategies.


Book Synopsis Catalysts Deactivation, Poisoning and Regeneration by : Luciana Lisi

Download or read book Catalysts Deactivation, Poisoning and Regeneration written by Luciana Lisi and published by MDPI. This book was released on 2019-10-01 with total page 254 pages. Available in PDF, EPUB and Kindle. Book excerpt: Catalyst lifetime represents one of the most crucial economic aspects in industrial catalytic processes, due to costly shutdowns, catalyst replacements, and proper disposal of spent materials. Not surprisingly, there is considerable motivation to understand and treat catalyst deactivation, poisoning, and regeneration, which causes this research topic to continue to grow. The complexity of catalyst poisoning obviously increases along with the increasing use of biomass/waste-derived/residual feedstocks and with requirements for cleaner and novel sustainable processes. This book collects 15 research papers providing insights into several scientific and technical aspects of catalyst poisoning and deactivation, proposing more tolerant catalyst formulations, and exploring possible regeneration strategies.

Catalyst Deactivation 1994

Catalyst Deactivation 1994

Author: G.F. Froment

Publisher: Elsevier

Published: 1994-09-08

Total Pages: 683

ISBN-13: 9780080887388

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Catalyst Deactivation 1994 was an expansion of earlier, highly successful symposia. The objective of the symposium was to promote a scientific approach of the phenomenon of catalyst deactivation which will contribute to the development of catalysts which are less subject to structural transformations and more resistant to poisons and coke formation. These aspects are dealt with in 12 plenary lectures, 48 oral presentations and 35 poster papers, which were critically selected from an impressive response from some 30 countries. Both fundamental and applied aspects were covered. The deactivation of catalysts in important industrial processes like fluid bed catalytic cracking hydrotreatment, hydrodesulfurization, catalytic reforming, hydrodenitrogenation, steam reforming, hydrodemetallization, hydrocracking, Fischer-Tropsch synthesis, propane dehydrogenation, phthalic anhydride synthesis received considerable attention. Mechanisms of poisoning, sintering and coking were further investigated and modelled and new experimental techniques for the characterization and the quantification of deactivation were also introduced.


Book Synopsis Catalyst Deactivation 1994 by : G.F. Froment

Download or read book Catalyst Deactivation 1994 written by G.F. Froment and published by Elsevier. This book was released on 1994-09-08 with total page 683 pages. Available in PDF, EPUB and Kindle. Book excerpt: Catalyst Deactivation 1994 was an expansion of earlier, highly successful symposia. The objective of the symposium was to promote a scientific approach of the phenomenon of catalyst deactivation which will contribute to the development of catalysts which are less subject to structural transformations and more resistant to poisons and coke formation. These aspects are dealt with in 12 plenary lectures, 48 oral presentations and 35 poster papers, which were critically selected from an impressive response from some 30 countries. Both fundamental and applied aspects were covered. The deactivation of catalysts in important industrial processes like fluid bed catalytic cracking hydrotreatment, hydrodesulfurization, catalytic reforming, hydrodenitrogenation, steam reforming, hydrodemetallization, hydrocracking, Fischer-Tropsch synthesis, propane dehydrogenation, phthalic anhydride synthesis received considerable attention. Mechanisms of poisoning, sintering and coking were further investigated and modelled and new experimental techniques for the characterization and the quantification of deactivation were also introduced.

Zeolite Microporous Solids: Synthesis, Structure, and Reactivity

Zeolite Microporous Solids: Synthesis, Structure, and Reactivity

Author: E.G. Derouane

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 635

ISBN-13: 9401126046

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Intensive research on zeolites, during the past thirty years, has resulted in a deep understanding of their chemistry and in a true zeolite science, including synthesis, structure, chemical and physical properties, and catalysis. These studies are the basis for the development and growth of several industrial processes applying zeolites for selective sorption, separation, and catalysis. In 1983, a NATO Advanced Study Institute was organized in Alcabideche (portugal) to establish the State-of-the-Art in Zeolite Science and Technology and to contribute to a better understanding of the structural properties of zeolites, the configurational constraints they may exert, and their effects in adsorption, diffusion, and catalysis. Since then, zeolite science has witnessed an almost exponential growth in published papers and patents, dealing with both fundamentals issues and original applications. The proposal of new procedures for zeolite synthesis, the development of novel and sophisticated physical techniques for zeolite characterization, the discovery of new zeolitic and related microporous materials, progresses in quantum chemistry and molecular modeling of zeolites, and the application of zeolites as catalysts for organic reactions have prompted increasing interest among the scientific community. An important and harmonious interaction between various domains of Physics, Chemistry, and Engineering resulted therefrom.


Book Synopsis Zeolite Microporous Solids: Synthesis, Structure, and Reactivity by : E.G. Derouane

Download or read book Zeolite Microporous Solids: Synthesis, Structure, and Reactivity written by E.G. Derouane and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 635 pages. Available in PDF, EPUB and Kindle. Book excerpt: Intensive research on zeolites, during the past thirty years, has resulted in a deep understanding of their chemistry and in a true zeolite science, including synthesis, structure, chemical and physical properties, and catalysis. These studies are the basis for the development and growth of several industrial processes applying zeolites for selective sorption, separation, and catalysis. In 1983, a NATO Advanced Study Institute was organized in Alcabideche (portugal) to establish the State-of-the-Art in Zeolite Science and Technology and to contribute to a better understanding of the structural properties of zeolites, the configurational constraints they may exert, and their effects in adsorption, diffusion, and catalysis. Since then, zeolite science has witnessed an almost exponential growth in published papers and patents, dealing with both fundamentals issues and original applications. The proposal of new procedures for zeolite synthesis, the development of novel and sophisticated physical techniques for zeolite characterization, the discovery of new zeolitic and related microporous materials, progresses in quantum chemistry and molecular modeling of zeolites, and the application of zeolites as catalysts for organic reactions have prompted increasing interest among the scientific community. An important and harmonious interaction between various domains of Physics, Chemistry, and Engineering resulted therefrom.

Zeolites in Catalysis

Zeolites in Catalysis

Author: Jiří Čejka

Publisher: Royal Society of Chemistry

Published: 2017-06-07

Total Pages: 547

ISBN-13: 1782627847

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Covering the breadth of zeolite chemistry and catalysis, this book provides the reader with a complete introduction to field, covering synthesis, structure, characterisation and applications. Beginning with the history of natural and synthetic zeolites, the reader will learn how zeolite structures are formed, synthetic routes, and experimental and theoretical structure determination techniques. Their industrial applications are covered in-depth, from their use in the petrochemical industry, through to fine chemicals and more specialised clinical applications. Novel zeolite materials are covered, including hierarchical zeolites and two-dimensional zeolites, showcasing modern developments in the field. This book is ideal for newcomers who need to get up to speed with zeolite chemistry, and also experienced researchers who will find this a modern, up-to-date guide.


Book Synopsis Zeolites in Catalysis by : Jiří Čejka

Download or read book Zeolites in Catalysis written by Jiří Čejka and published by Royal Society of Chemistry. This book was released on 2017-06-07 with total page 547 pages. Available in PDF, EPUB and Kindle. Book excerpt: Covering the breadth of zeolite chemistry and catalysis, this book provides the reader with a complete introduction to field, covering synthesis, structure, characterisation and applications. Beginning with the history of natural and synthetic zeolites, the reader will learn how zeolite structures are formed, synthetic routes, and experimental and theoretical structure determination techniques. Their industrial applications are covered in-depth, from their use in the petrochemical industry, through to fine chemicals and more specialised clinical applications. Novel zeolite materials are covered, including hierarchical zeolites and two-dimensional zeolites, showcasing modern developments in the field. This book is ideal for newcomers who need to get up to speed with zeolite chemistry, and also experienced researchers who will find this a modern, up-to-date guide.

Deactivation and Poisoning of Catalysts

Deactivation and Poisoning of Catalysts

Author: J. Oudar

Publisher: CRC Press

Published: 1985-07-02

Total Pages: 356

ISBN-13: 9780824773380

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Deactivation and Poisoning of Catalysts presents the most current research in the area of heterogeneous catalysis. It focuses on the chemically induced effects associated with bonded surface species that cause catalyst activity decline -- and in some cases a change in catalyst specificity. In addition, this volume examines poisoning of dispersed metal catalysts ... the thermodynamics of sulfur-metal and carbon-metal interactions ... model poisoning reactions on single crystals ... deactivation in petroleum refining and petrochemical processes ... coking of metal catalysts ... and more. The new approaches and solutions to catalyst deactivation and poisoning presented in this guide are invaluable to all heterogeneous catalysis specialists, including chemical and petroleum engineers, and surface, synthetic, physical, and industrial chemists. Book jacket.


Book Synopsis Deactivation and Poisoning of Catalysts by : J. Oudar

Download or read book Deactivation and Poisoning of Catalysts written by J. Oudar and published by CRC Press. This book was released on 1985-07-02 with total page 356 pages. Available in PDF, EPUB and Kindle. Book excerpt: Deactivation and Poisoning of Catalysts presents the most current research in the area of heterogeneous catalysis. It focuses on the chemically induced effects associated with bonded surface species that cause catalyst activity decline -- and in some cases a change in catalyst specificity. In addition, this volume examines poisoning of dispersed metal catalysts ... the thermodynamics of sulfur-metal and carbon-metal interactions ... model poisoning reactions on single crystals ... deactivation in petroleum refining and petrochemical processes ... coking of metal catalysts ... and more. The new approaches and solutions to catalyst deactivation and poisoning presented in this guide are invaluable to all heterogeneous catalysis specialists, including chemical and petroleum engineers, and surface, synthetic, physical, and industrial chemists. Book jacket.

Zeolite Catalysts

Zeolite Catalysts

Author: Subhash Bhatia

Publisher: CRC Press

Published: 2020-07-24

Total Pages: 306

ISBN-13: 1000141764

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Presented in an easy-to-read form, this book on zeolite catalysis cover all aspects of the subject. It focuses on synthesis, structure, diffusion, deactivation, and industrial applications. This book is an ideal text for courses on catalysis or as a supplementary text for those studying applied or industrial chemistry. It is also a useful resource for anyone who works with zeolites as catalysts in the laboratory, pilot plants, or commercial installations.


Book Synopsis Zeolite Catalysts by : Subhash Bhatia

Download or read book Zeolite Catalysts written by Subhash Bhatia and published by CRC Press. This book was released on 2020-07-24 with total page 306 pages. Available in PDF, EPUB and Kindle. Book excerpt: Presented in an easy-to-read form, this book on zeolite catalysis cover all aspects of the subject. It focuses on synthesis, structure, diffusion, deactivation, and industrial applications. This book is an ideal text for courses on catalysis or as a supplementary text for those studying applied or industrial chemistry. It is also a useful resource for anyone who works with zeolites as catalysts in the laboratory, pilot plants, or commercial installations.