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Heterogeneous Photocatalysis Using Inorganic Semiconductor Solids

Author: Umar Ibrahim Gaya

Publisher: Springer Science & Business Media

Published: 2013-11-08

Total Pages: 222

ISBN-13: 9400777752

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This book underscores the essential principles of photocatalysis and provides an update on its scientific foundations, research advances, and current opinions, and interpretations. It consists of an introduction to the concepts that form the backbone of photocatalysis, from the principles of solid-state chemistry and physics to the role of reactive oxidizing species. Having recognised the organic link with chemical kinetics, part of the book describes kinetic concepts as they apply to photocatalysis. The dependence of rate on the reaction conditions and parameters is detailed, the retrospective and prospective aspects of the mechanism of photocatalysis are highlighted, and the adsorption models, photocatalytic rate expressions, and kinetic disguises are examined. This book also discusses the structure, property, and activity relationship of prototypical semiconductor photocatalysts and reviews how to extend their spectral absorption to the visible region to enable the effective use of visible solar spectrum. Lastly, it presents strategies for deriving substantially improved photoactivity from semiconductor materials to support the latest applications and potential trends.

Book Synopsis Heterogeneous Photocatalysis Using Inorganic Semiconductor Solids by : Umar Ibrahim Gaya

Download or read book Heterogeneous Photocatalysis Using Inorganic Semiconductor Solids written by Umar Ibrahim Gaya and published by Springer Science & Business Media. This book was released on 2013-11-08 with total page 222 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book underscores the essential principles of photocatalysis and provides an update on its scientific foundations, research advances, and current opinions, and interpretations. It consists of an introduction to the concepts that form the backbone of photocatalysis, from the principles of solid-state chemistry and physics to the role of reactive oxidizing species. Having recognised the organic link with chemical kinetics, part of the book describes kinetic concepts as they apply to photocatalysis. The dependence of rate on the reaction conditions and parameters is detailed, the retrospective and prospective aspects of the mechanism of photocatalysis are highlighted, and the adsorption models, photocatalytic rate expressions, and kinetic disguises are examined. This book also discusses the structure, property, and activity relationship of prototypical semiconductor photocatalysts and reviews how to extend their spectral absorption to the visible region to enable the effective use of visible solar spectrum. Lastly, it presents strategies for deriving substantially improved photoactivity from semiconductor materials to support the latest applications and potential trends.

Heterogeneous Photocatalysis Using Inorganic Semiconductor Solids

Author: Umar Gaya

Publisher: Springer

Published: 2013-11-27

Total Pages: 213

ISBN-13: 9789400777767

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Book Synopsis Heterogeneous Photocatalysis Using Inorganic Semiconductor Solids by : Umar Gaya

Download or read book Heterogeneous Photocatalysis Using Inorganic Semiconductor Solids written by Umar Gaya and published by Springer. This book was released on 2013-11-27 with total page 213 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book underscores the essential principles of photocatalysis and provides an update on its scientific foundations, research advances, and current opinions, and interpretations. It consists of an introduction to the concepts that form the backbone of photocatalysis, from the principles of solid-state chemistry and physics to the role of reactive oxidizing species. Having recognised the organic link with chemical kinetics, part of the book describes kinetic concepts as they apply to photocatalysis. The dependence of rate on the reaction conditions and parameters is detailed, the retrospective and prospective aspects of the mechanism of photocatalysis are highlighted, and the adsorption models, photocatalytic rate expressions, and kinetic disguises are examined. This book also discusses the structure, property, and activity relationship of prototypical semiconductor photocatalysts and reviews how to extend their spectral absorption to the visible region to enable the effective use of visible solar spectrum. Lastly, it presents strategies for deriving substantially improved photoactivity from semiconductor materials to support the latest applications and potential trends.

Heterogeneous Photocatalysis

Author: Giuseppe Marcì

Publisher: Elsevier

Published: 2019-02-21

Total Pages: 290

ISBN-13: 0444640169

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Heterogeneous Photocatalysis: Relationships with Heterogeneous Catalysis and Perspectives highlights the differences between thermal-catalysis and photo-catalysis and indicates borderlines, in particular, the possible synergism between them. The book outlines the basic aspect of thermal- and photo-catalysis, along with the most important characterization techniques. In addition, it presents case studies of thermal-catalytic and photo-catalytic or thermal-photo-catalytic reactions and includes a comparison between the results obtained using an inorganic solid as thermal catalyst and photocatalyst for the same reaction, and in the same setup. Final sections offer information on the preparation methods of (photo)catalysts, various techniques used for their characterization, engineering and economical aspects. This book will be a valuable reference source for students and researchers involved in heterogeneous photocatalysis and catalysis, chemistry, chemical engineering, materials science, materials engineering, environment engineering, nanotechnology and green chemistry. Provides selective methods for the preparation of microcrystalline/nanocrystalline solids or films used in catalytic and photocatalytic processes Describes (photo)reactions that can be carried out catalytically and/or photocatalytically Outlines the different mechanisms, yields and experimental conditions under which photocatalytic reactions can take place Describes various (photo)reactors and set ups under which the photacatalytic reactions can be carried out Provides an economic assessment to understand the feasibility of some photocatalytic reactions

Book Synopsis Heterogeneous Photocatalysis by : Giuseppe Marcì

Download or read book Heterogeneous Photocatalysis written by Giuseppe Marcì and published by Elsevier. This book was released on 2019-02-21 with total page 290 pages. Available in PDF, EPUB and Kindle. Book excerpt: Heterogeneous Photocatalysis: Relationships with Heterogeneous Catalysis and Perspectives highlights the differences between thermal-catalysis and photo-catalysis and indicates borderlines, in particular, the possible synergism between them. The book outlines the basic aspect of thermal- and photo-catalysis, along with the most important characterization techniques. In addition, it presents case studies of thermal-catalytic and photo-catalytic or thermal-photo-catalytic reactions and includes a comparison between the results obtained using an inorganic solid as thermal catalyst and photocatalyst for the same reaction, and in the same setup. Final sections offer information on the preparation methods of (photo)catalysts, various techniques used for their characterization, engineering and economical aspects. This book will be a valuable reference source for students and researchers involved in heterogeneous photocatalysis and catalysis, chemistry, chemical engineering, materials science, materials engineering, environment engineering, nanotechnology and green chemistry. Provides selective methods for the preparation of microcrystalline/nanocrystalline solids or films used in catalytic and photocatalytic processes Describes (photo)reactions that can be carried out catalytically and/or photocatalytically Outlines the different mechanisms, yields and experimental conditions under which photocatalytic reactions can take place Describes various (photo)reactors and set ups under which the photacatalytic reactions can be carried out Provides an economic assessment to understand the feasibility of some photocatalytic reactions

Heterogeneous Photocatalysis

Author: M. Schiavello

Publisher:

Published: 1997-10-09

Total Pages: 218

ISBN-13:

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Photocatalysis is a reaction which is accelerated by light while a heterogeneous reaction consists of two phases ( a solid and a liquid for example). Heterogeneous Photocatalysis is a fast developing science which to date has not been fully detailed in a monograph. This title discusses the basic principles of heterogeneous photocatalysis and describes the bulk and surface properties of semiconductors. Applications of various types of photoreactions are described and the problems related to the modeling and design of photoreactors are covered.

Book Synopsis Heterogeneous Photocatalysis by : M. Schiavello

Download or read book Heterogeneous Photocatalysis written by M. Schiavello and published by . This book was released on 1997-10-09 with total page 218 pages. Available in PDF, EPUB and Kindle. Book excerpt: Photocatalysis is a reaction which is accelerated by light while a heterogeneous reaction consists of two phases ( a solid and a liquid for example). Heterogeneous Photocatalysis is a fast developing science which to date has not been fully detailed in a monograph. This title discusses the basic principles of heterogeneous photocatalysis and describes the bulk and surface properties of semiconductors. Applications of various types of photoreactions are described and the problems related to the modeling and design of photoreactors are covered.

Heterogeneous Photocatalysis

Author: Mario J. Muñoz-Batista

Publisher: Springer Nature

Published: 2020-07-01

Total Pages: 301

ISBN-13: 3030494926

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The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field. The chapter "Mechanochemical Forces as a Synthetic Tool for Zero and One-Dimensional Titanium Oxide-Based Nano-photocatalysts" is available open access under a CC BY 4.0 License via link.springer.com.

Book Synopsis Heterogeneous Photocatalysis by : Mario J. Muñoz-Batista

Download or read book Heterogeneous Photocatalysis written by Mario J. Muñoz-Batista and published by Springer Nature. This book was released on 2020-07-01 with total page 301 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field. The chapter "Mechanochemical Forces as a Synthetic Tool for Zero and One-Dimensional Titanium Oxide-Based Nano-photocatalysts" is available open access under a CC BY 4.0 License via link.springer.com.

Catalysis by Precious Metals, Past and Future

Author: Marcela Martinez Tejada

Publisher: MDPI

Published: 2020-04-15

Total Pages: 204

ISBN-13: 3039287222

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The future of the precious metals is shiny and resistant. Although expensive and potentially replaceable by transition metal catalysts, precious metal implementation in research and industry shows potential. These metals catalyze oxidation and hydrogenation due to their dissociative behavior toward hydrogen and oxygen, dehydrogenation, isomerization, and aromatization, etc. The precious metal catalysts, especially platinum-based catalysts, are involved in a variety of industrial processes. Examples include Pt–Rh gauze for nitric acid production, the Pt/Al2O3 catalyst for cyclohexane and propylene production, and Pd/Al2O3 catalysts for petrochemical hydropurification reactions, etc. A quick search of the number of published articles in the last five years containing a combination of corresponding “metals” (Pt, Pd, Ru, Rh and Au) and “catalysts” as keywords indicates the importance of the Pt catalysts, but also the continuous increase in the contribution of Pd and Au. This Special Issue reveals the importance of precious metals in catalysis and focuses on mono- and bi-metallic formulations of any supported precious metals and their promotional catalytic effect of other transition metals. The application of precious metals in diverse reactions, either homogeneous or heterogeneous, and studies of the preparation, characterization, and applications of the supported precious metal catalysts, are presented.

Book Synopsis Catalysis by Precious Metals, Past and Future by : Marcela Martinez Tejada

Download or read book Catalysis by Precious Metals, Past and Future written by Marcela Martinez Tejada and published by MDPI. This book was released on 2020-04-15 with total page 204 pages. Available in PDF, EPUB and Kindle. Book excerpt: The future of the precious metals is shiny and resistant. Although expensive and potentially replaceable by transition metal catalysts, precious metal implementation in research and industry shows potential. These metals catalyze oxidation and hydrogenation due to their dissociative behavior toward hydrogen and oxygen, dehydrogenation, isomerization, and aromatization, etc. The precious metal catalysts, especially platinum-based catalysts, are involved in a variety of industrial processes. Examples include Pt–Rh gauze for nitric acid production, the Pt/Al2O3 catalyst for cyclohexane and propylene production, and Pd/Al2O3 catalysts for petrochemical hydropurification reactions, etc. A quick search of the number of published articles in the last five years containing a combination of corresponding “metals” (Pt, Pd, Ru, Rh and Au) and “catalysts” as keywords indicates the importance of the Pt catalysts, but also the continuous increase in the contribution of Pd and Au. This Special Issue reveals the importance of precious metals in catalysis and focuses on mono- and bi-metallic formulations of any supported precious metals and their promotional catalytic effect of other transition metals. The application of precious metals in diverse reactions, either homogeneous or heterogeneous, and studies of the preparation, characterization, and applications of the supported precious metal catalysts, are presented.

Semiconductor Solar Photocatalysts

Author: Jiaguo Yu

Publisher: John Wiley & Sons

Published: 2022-03-14

Total Pages: 514

ISBN-13: 3527349596

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Provides a timely overview of basic principles and significant advances of semiconductor-based photocatalysts for solar energy conversion Semiconductor Solar Photocatalysts: Fundamentals and Applications presents a systematic, in-depth summary of both fundamental and cutting-edge research in novel photocatalytic systems. Focusing on photocatalysts with vast potential for efficient utilization of solar energy, this up-to-date volume covers heterojunction systems, graphene-based photocatalysts, organic semiconductor photocatalysts, metal sulfide semiconductor photocatalysts, and graphitic carbon nitride-based photocatalysts. Organized into six chapters, the text opens with a detailed introduction to the history, design principles, modification strategies, and performance evaluation methods of solar energy photocatalysis. The remaining chapters provide detailed discussion of various novel photocatalytic systems such as direct Z-scheme and S-scheme photocatalysts, organic polymers, and covalent organic frameworks. This authoritative resource: Explains the essential concepts of solar energy photocatalysis and heterojunction systems for photocatalysis Reviews interesting structures and new applications of semiconductor photocatalysts Features contributions from an international panel of leading researchers in the field Includes extensive references and numerous tables, figures, and color illustrations Semiconductor Solar Photocatalysts: Fundamentals and Applications is valuable resource for all catalytic chemists, materials scientists, inorganic and physical chemists, chemical engineers, and physicists working in the semiconductor industry.

Book Synopsis Semiconductor Solar Photocatalysts by : Jiaguo Yu

Download or read book Semiconductor Solar Photocatalysts written by Jiaguo Yu and published by John Wiley & Sons. This book was released on 2022-03-14 with total page 514 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides a timely overview of basic principles and significant advances of semiconductor-based photocatalysts for solar energy conversion Semiconductor Solar Photocatalysts: Fundamentals and Applications presents a systematic, in-depth summary of both fundamental and cutting-edge research in novel photocatalytic systems. Focusing on photocatalysts with vast potential for efficient utilization of solar energy, this up-to-date volume covers heterojunction systems, graphene-based photocatalysts, organic semiconductor photocatalysts, metal sulfide semiconductor photocatalysts, and graphitic carbon nitride-based photocatalysts. Organized into six chapters, the text opens with a detailed introduction to the history, design principles, modification strategies, and performance evaluation methods of solar energy photocatalysis. The remaining chapters provide detailed discussion of various novel photocatalytic systems such as direct Z-scheme and S-scheme photocatalysts, organic polymers, and covalent organic frameworks. This authoritative resource: Explains the essential concepts of solar energy photocatalysis and heterojunction systems for photocatalysis Reviews interesting structures and new applications of semiconductor photocatalysts Features contributions from an international panel of leading researchers in the field Includes extensive references and numerous tables, figures, and color illustrations Semiconductor Solar Photocatalysts: Fundamentals and Applications is valuable resource for all catalytic chemists, materials scientists, inorganic and physical chemists, chemical engineers, and physicists working in the semiconductor industry.

Graphene Oxide-Metal Oxide and other Graphene Oxide-Based Composites in Photocatalysis and Electrocatalysis

Author: Jiaguo Yu

Publisher: Elsevier

Published: 2022-06-24

Total Pages: 308

ISBN-13: 0323852882

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Graphene Oxide-Metal Oxide and other Graphene Oxide-Based Composites in Photocatalysis and Electrocatalysis reflects on recent progress and challenges in graphene-metal oxide composites. The book reviews synthetic strategies, characterization methods and applications in photocatalysis and electrocatalysis. Graphene-metal oxides, graphene-novel metals and other composites intended for sustainable energy production, energy storage, and environmental development such as H2 production, CO2 reduction, pollutant removal, supercapacitors and lithium ion batteries are covered. Overall, this book presents a comprehensive, systematic, and up-to-date summary on graphene oxide-based materials. Graphene oxide and related composite materials bring new perspectives and prospects to both photocatalysts and electrocatalysts. The collective and synergistic effect between graphene oxide and metal oxide are manifold. The significance of the relationship among these groups of materials, their structures and performance is emphasized. Introduces the fundamentals of graphene oxides, their derivatives, common processes, principles and requirements for photocatalysis and electrocatalysis Reviews graphene-oxides for photocatalysis applications in H2 production, CO2 reduction, environment remediation, and more Covers graphene-oxides for electrocatalysis applications in energy, including supercapacitors and lithium-ion batteries

Book Synopsis Graphene Oxide-Metal Oxide and other Graphene Oxide-Based Composites in Photocatalysis and Electrocatalysis by : Jiaguo Yu

Download or read book Graphene Oxide-Metal Oxide and other Graphene Oxide-Based Composites in Photocatalysis and Electrocatalysis written by Jiaguo Yu and published by Elsevier. This book was released on 2022-06-24 with total page 308 pages. Available in PDF, EPUB and Kindle. Book excerpt: Graphene Oxide-Metal Oxide and other Graphene Oxide-Based Composites in Photocatalysis and Electrocatalysis reflects on recent progress and challenges in graphene-metal oxide composites. The book reviews synthetic strategies, characterization methods and applications in photocatalysis and electrocatalysis. Graphene-metal oxides, graphene-novel metals and other composites intended for sustainable energy production, energy storage, and environmental development such as H2 production, CO2 reduction, pollutant removal, supercapacitors and lithium ion batteries are covered. Overall, this book presents a comprehensive, systematic, and up-to-date summary on graphene oxide-based materials. Graphene oxide and related composite materials bring new perspectives and prospects to both photocatalysts and electrocatalysts. The collective and synergistic effect between graphene oxide and metal oxide are manifold. The significance of the relationship among these groups of materials, their structures and performance is emphasized. Introduces the fundamentals of graphene oxides, their derivatives, common processes, principles and requirements for photocatalysis and electrocatalysis Reviews graphene-oxides for photocatalysis applications in H2 production, CO2 reduction, environment remediation, and more Covers graphene-oxides for electrocatalysis applications in energy, including supercapacitors and lithium-ion batteries

Green Photocatalytic Semiconductors

Author: Seema Garg

Publisher: Springer Nature

Published: 2021-09-20

Total Pages: 855

ISBN-13: 303077371X

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This book comprises a detailed overview on the role of photocatalysts for environmental remediation, hydrogen production and carbon dioxide reduction. Effective ways to enhance the photocatalytic activity of the material via doping, hybrid material, laser light and nanocomposites have been discussed in this book. The book also further elaborates the role of metal nanoparticles, rare earth doping, sensitizers, surface oxygen vacancy, interface engineering and band gap engineering for enhancing the photocatalytic activity. An approach to recover the photocatalytic material via immobilization is also presented. This book brings to light much of the recent research in the development of such semiconductor photocatalytic systems. The book will thus be of relevance to researchers in the field of: material science, environmental science & technology, photocatalytic applications, newer methods of energy generation & conversion and industrial applications.

Book Synopsis Green Photocatalytic Semiconductors by : Seema Garg

Download or read book Green Photocatalytic Semiconductors written by Seema Garg and published by Springer Nature. This book was released on 2021-09-20 with total page 855 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book comprises a detailed overview on the role of photocatalysts for environmental remediation, hydrogen production and carbon dioxide reduction. Effective ways to enhance the photocatalytic activity of the material via doping, hybrid material, laser light and nanocomposites have been discussed in this book. The book also further elaborates the role of metal nanoparticles, rare earth doping, sensitizers, surface oxygen vacancy, interface engineering and band gap engineering for enhancing the photocatalytic activity. An approach to recover the photocatalytic material via immobilization is also presented. This book brings to light much of the recent research in the development of such semiconductor photocatalytic systems. The book will thus be of relevance to researchers in the field of: material science, environmental science & technology, photocatalytic applications, newer methods of energy generation & conversion and industrial applications.

Metal Semiconductor Core-shell Nanostructures for Energy and Environmental Applications

Author: Raju Kumar Gupta

Publisher: Elsevier

Published: 2017-04-28

Total Pages: 218

ISBN-13: 0128124458

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Metal Semiconductor Core-Shell Nanostructures for Energy and Environmental Applications provides a concise, scholarly overview of current research into the characterization of metal semiconductor core-shell nanostructures; the book shows how their properties can be best used in energy and environmental applications, particularly for solar cell and catalysis application. Coverage is also given to the effect of metal nanoparticle for charge generation or charge separation. The book is a valuable resource for academic researchers working in the areas of nanotechnology, sustainable energy and chemical engineering, and is also of great use to engineers working in photovoltaic and pollution industries. Includes a clear method for synthesis of core-shell nanomaterials Explores how metal semiconductor core-shell nanostructures can be used to improve the efficiency of solar cells Explains how the characteristics of metal semiconductor core-shell nanostructures make them particularly useful for sustainable energy and environmental applications

Book Synopsis Metal Semiconductor Core-shell Nanostructures for Energy and Environmental Applications by : Raju Kumar Gupta

Download or read book Metal Semiconductor Core-shell Nanostructures for Energy and Environmental Applications written by Raju Kumar Gupta and published by Elsevier. This book was released on 2017-04-28 with total page 218 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal Semiconductor Core-Shell Nanostructures for Energy and Environmental Applications provides a concise, scholarly overview of current research into the characterization of metal semiconductor core-shell nanostructures; the book shows how their properties can be best used in energy and environmental applications, particularly for solar cell and catalysis application. Coverage is also given to the effect of metal nanoparticle for charge generation or charge separation. The book is a valuable resource for academic researchers working in the areas of nanotechnology, sustainable energy and chemical engineering, and is also of great use to engineers working in photovoltaic and pollution industries. Includes a clear method for synthesis of core-shell nanomaterials Explores how metal semiconductor core-shell nanostructures can be used to improve the efficiency of solar cells Explains how the characteristics of metal semiconductor core-shell nanostructures make them particularly useful for sustainable energy and environmental applications