Metal Complexes Containing Boron Based Ligands

Metal Complexes Containing Boron Based Ligands

Author: Gareth Owen

Publisher: MDPI

Published: 2019-10-30

Total Pages: 110

ISBN-13: 3039215841

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Boron-based compounds have been utilized as ligands within transition metal complexes for many decades. The diversity of such compounds in terms of varying functional groups is truly exceptional. Boron compounds are of high interest due to the great potential to modify the substituents around the boron center and to produce a broad range of structural motifs. The many different ways these compounds can coordinate or interact with transition metal centers is astonishing. Examples of transition metal complexes containing boron-based ligands include scorpionates, cluster-type borane- and carboranes, borates, and phosphine-stabilized borylene ligands. This Special Issue brings together a collection of articles focusing on recent developments in the aforementioned boron-based ligands. The articles reported in this book will provide the reader with an overview of the types of boron-based ligands which are currently being researched in groups around the world.


Book Synopsis Metal Complexes Containing Boron Based Ligands by : Gareth Owen

Download or read book Metal Complexes Containing Boron Based Ligands written by Gareth Owen and published by MDPI. This book was released on 2019-10-30 with total page 110 pages. Available in PDF, EPUB and Kindle. Book excerpt: Boron-based compounds have been utilized as ligands within transition metal complexes for many decades. The diversity of such compounds in terms of varying functional groups is truly exceptional. Boron compounds are of high interest due to the great potential to modify the substituents around the boron center and to produce a broad range of structural motifs. The many different ways these compounds can coordinate or interact with transition metal centers is astonishing. Examples of transition metal complexes containing boron-based ligands include scorpionates, cluster-type borane- and carboranes, borates, and phosphine-stabilized borylene ligands. This Special Issue brings together a collection of articles focusing on recent developments in the aforementioned boron-based ligands. The articles reported in this book will provide the reader with an overview of the types of boron-based ligands which are currently being researched in groups around the world.

Metal Complexes Containing Boron Based Ligands

Metal Complexes Containing Boron Based Ligands

Author: Gareth Owen

Publisher:

Published: 2019

Total Pages: 1

ISBN-13: 9783039215850

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Boron-based compounds have been utilized as ligands within transition metal complexes for many decades. The diversity of such compounds in terms of varying functional groups is truly exceptional. Boron compounds are of high interest due to the great potential to modify the substituents around the boron center and to produce a broad range of structural motifs. The many different ways these compounds can coordinate or interact with transition metal centers is astonishing. Examples of transition metal complexes containing boron-based ligands include scorpionates, cluster-type borane- and carboranes, borates, and phosphine-stabilized borylene ligands. This Special Issue brings together a collection of articles focusing on recent developments in the aforementioned boron-based ligands. The articles reported in this book will provide the reader with an overview of the types of boron-based ligands which are currently being researched in groups around the world.


Book Synopsis Metal Complexes Containing Boron Based Ligands by : Gareth Owen

Download or read book Metal Complexes Containing Boron Based Ligands written by Gareth Owen and published by . This book was released on 2019 with total page 1 pages. Available in PDF, EPUB and Kindle. Book excerpt: Boron-based compounds have been utilized as ligands within transition metal complexes for many decades. The diversity of such compounds in terms of varying functional groups is truly exceptional. Boron compounds are of high interest due to the great potential to modify the substituents around the boron center and to produce a broad range of structural motifs. The many different ways these compounds can coordinate or interact with transition metal centers is astonishing. Examples of transition metal complexes containing boron-based ligands include scorpionates, cluster-type borane- and carboranes, borates, and phosphine-stabilized borylene ligands. This Special Issue brings together a collection of articles focusing on recent developments in the aforementioned boron-based ligands. The articles reported in this book will provide the reader with an overview of the types of boron-based ligands which are currently being researched in groups around the world.

Metal Complexes Containing Boron Based Ligands

Metal Complexes Containing Boron Based Ligands

Author:

Publisher:

Published: 2019

Total Pages: 0

ISBN-13:

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Boron-based compounds have been utilized as ligands within transition metal complexes for many decades. The diversity of such compounds in terms of varying functional groups is truly exceptional. Boron compounds are of high interest due to the great potential to modify the substituents around the boron center and to produce a broad range of structural motifs. The many different ways these compounds can coordinate or interact with transition metal centers is astonishing. Examples of transition metal complexes containing boron-based ligands include scorpionates, cluster-type borane- and carboranes, borates, and phosphine-stabilized borylene ligands. This Special Issue brings together a collection of articles focusing on recent developments in the aforementioned boron-based ligands. The articles reported in this book will provide the reader with an overview of the types of boron-based ligands which are currently being researched in groups around the world.


Book Synopsis Metal Complexes Containing Boron Based Ligands by :

Download or read book Metal Complexes Containing Boron Based Ligands written by and published by . This book was released on 2019 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Boron-based compounds have been utilized as ligands within transition metal complexes for many decades. The diversity of such compounds in terms of varying functional groups is truly exceptional. Boron compounds are of high interest due to the great potential to modify the substituents around the boron center and to produce a broad range of structural motifs. The many different ways these compounds can coordinate or interact with transition metal centers is astonishing. Examples of transition metal complexes containing boron-based ligands include scorpionates, cluster-type borane- and carboranes, borates, and phosphine-stabilized borylene ligands. This Special Issue brings together a collection of articles focusing on recent developments in the aforementioned boron-based ligands. The articles reported in this book will provide the reader with an overview of the types of boron-based ligands which are currently being researched in groups around the world.

Metal Interactions with Boron Clusters

Metal Interactions with Boron Clusters

Author: Russell N. Grimes

Publisher: Springer Science & Business Media

Published: 2013-11-11

Total Pages: 335

ISBN-13: 1489921540

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Molecular clusters, in the broad sense that the term is commonly understood, today comprise an enormous class of species extending into virtually every important area of chemistry: "naked" metal clusters, transition metal carbonyl clusters, hydrocarbon cages such as cubane (C H ) and dodecahedrane (C H ), 8 8 20 20 organometallic cluster complexes, enzymes containing Fe S or MoFe S 4 4 3 4 cores, high polymers based on carborane units, and, of course, the many kinds of polyhedral borane species. So large is the area spanned by these diverse classes that any attempt to deal with them comprehensively in one volume would, to say the least, be ambitious-and also premature. We are presently at a stage where intriguing relationships between the various cluster families are becoming apparent (particularly in terms of bonding descriptions), and despite large dif ferences in their chemistry an underlying unity is gradually developing in the field. For example, structural changes occurring in Fe S cores as electrons are 4 4 pumped in and out, in some measure resemble those observed in boranes and carboranes. The cleavage of alkynes via incorporation into carborane cages and subsequent cage rearrangement, a sequence familiar to boron chemists, is a thermodynamically favored process which may be related to the behavior of unsaturated hydrocarbons on metal surfaces; analogies of this sort have drawn attention from theorists and experimentalists.


Book Synopsis Metal Interactions with Boron Clusters by : Russell N. Grimes

Download or read book Metal Interactions with Boron Clusters written by Russell N. Grimes and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 335 pages. Available in PDF, EPUB and Kindle. Book excerpt: Molecular clusters, in the broad sense that the term is commonly understood, today comprise an enormous class of species extending into virtually every important area of chemistry: "naked" metal clusters, transition metal carbonyl clusters, hydrocarbon cages such as cubane (C H ) and dodecahedrane (C H ), 8 8 20 20 organometallic cluster complexes, enzymes containing Fe S or MoFe S 4 4 3 4 cores, high polymers based on carborane units, and, of course, the many kinds of polyhedral borane species. So large is the area spanned by these diverse classes that any attempt to deal with them comprehensively in one volume would, to say the least, be ambitious-and also premature. We are presently at a stage where intriguing relationships between the various cluster families are becoming apparent (particularly in terms of bonding descriptions), and despite large dif ferences in their chemistry an underlying unity is gradually developing in the field. For example, structural changes occurring in Fe S cores as electrons are 4 4 pumped in and out, in some measure resemble those observed in boranes and carboranes. The cleavage of alkynes via incorporation into carborane cages and subsequent cage rearrangement, a sequence familiar to boron chemists, is a thermodynamically favored process which may be related to the behavior of unsaturated hydrocarbons on metal surfaces; analogies of this sort have drawn attention from theorists and experimentalists.

Contemporary Metal Boron Chemistry I

Contemporary Metal Boron Chemistry I

Author: Todd B. Marder

Publisher: Springer Science & Business Media

Published: 2008-07-11

Total Pages: 227

ISBN-13: 3540786333

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With information that will remain valid for years, this series presents critical reviews of the present position and future trends in modern research into chemical structure and bonding. It features concise reports, each written by world-renowned experts.


Book Synopsis Contemporary Metal Boron Chemistry I by : Todd B. Marder

Download or read book Contemporary Metal Boron Chemistry I written by Todd B. Marder and published by Springer Science & Business Media. This book was released on 2008-07-11 with total page 227 pages. Available in PDF, EPUB and Kindle. Book excerpt: With information that will remain valid for years, this series presents critical reviews of the present position and future trends in modern research into chemical structure and bonding. It features concise reports, each written by world-renowned experts.

Organometallic Chemistry Volume 43

Organometallic Chemistry Volume 43

Author: Paul I. P. Elliott

Publisher: Royal Society of Chemistry

Published: 2020-11-09

Total Pages: 247

ISBN-13: 1788016912

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Providing an invaluable resource, this volume contains analysed, evaluated and distilled information on the latest in organometallic and coordination chemistry research and emerging fields. With the increase in volume, velocity and variety of information, researchers can find it difficult to keep up to date with the literature in their field. The reviews range in scope and include recent advances in chromium coordination chemistry, borohydride and borane ligand architectures supported by heterocyclic units and discussion on behaviours of novel ruthenium (II) complexes. This volume is a key reference for researchers in academic and industrial settings.


Book Synopsis Organometallic Chemistry Volume 43 by : Paul I. P. Elliott

Download or read book Organometallic Chemistry Volume 43 written by Paul I. P. Elliott and published by Royal Society of Chemistry. This book was released on 2020-11-09 with total page 247 pages. Available in PDF, EPUB and Kindle. Book excerpt: Providing an invaluable resource, this volume contains analysed, evaluated and distilled information on the latest in organometallic and coordination chemistry research and emerging fields. With the increase in volume, velocity and variety of information, researchers can find it difficult to keep up to date with the literature in their field. The reviews range in scope and include recent advances in chromium coordination chemistry, borohydride and borane ligand architectures supported by heterocyclic units and discussion on behaviours of novel ruthenium (II) complexes. This volume is a key reference for researchers in academic and industrial settings.

Synthesis of Ionic Boron Amphiphilic Diblock Copolymers and Pyridylborate Ligands for Transition Metal Complexes

Synthesis of Ionic Boron Amphiphilic Diblock Copolymers and Pyridylborate Ligands for Transition Metal Complexes

Author: Chengzhong Cui

Publisher:

Published: 2010

Total Pages: 300

ISBN-13:

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Atom transfer radical polymerization (ATRP) has been successfully used to prepare well-defined poly(trimethylsilyl)styrenes and the diblock copolymers, poly(trimethylsilyl)styrene-b-polystyrene, with controlled molecular weight and low polydispersity. Quantitative replacement of trimethylsilyl groups with boron tribromide in dichloromethane provided an important highly Lewis acidic intermediate that have allowed for the preparation of novel boron containing borate and boronium types of homopolymers and amphiphilic diblock copolymers with different post-polymerization modification processes. Characterizations including NMR spectroscopy, gel permeation chromatography (GPC) and the representative elemental analysis have been applied to confirm the quantitative transformations from the silylated polymers to the boron containing ionic polymers. The self-assembly properties in block selective solvents of the amphiphilic block copolymers were extensively studied. Most importantly, through an electro-static interaction, the weakly coordinating pentafluorophenyl borate block copolymers were successfully used to attach an organo-rhodium catalyst and then underwent self-assembly in selective solvent to give rise to transition metal containing micelles with well-defined nanostructures. In the last chapter, synthesis and characterizations of a variety of novel multidentate pyridylborate ligands are described. An appropriate procedure for synthesis of 2-pyridyl magnesium chloride in a usual dimeric structure was developed. The 2-pyridyl magnesium chloride was then used to react with different arylbromoboranes in dichloromethane or toluene affording different multidentate ligands. The tris(2-pyridyl)borate ligands were the first pyridine based tripod ligands with a boron atom as the bridging head and their complexation with Fe(II) was studied by cyclic voltammetry (CV) and UV-vis spectroscopy. All the structures of the ligands and metal complexes were determined by single crystal X-ray spectroscopy. The styryltris(2-pyridyl)borate monomer was successfully polymerized in a free radical polymerization to give a polymer with good yield and high molecular weight. NMR analysis was used to confirm the formation of this novel polydentate polymer.


Book Synopsis Synthesis of Ionic Boron Amphiphilic Diblock Copolymers and Pyridylborate Ligands for Transition Metal Complexes by : Chengzhong Cui

Download or read book Synthesis of Ionic Boron Amphiphilic Diblock Copolymers and Pyridylborate Ligands for Transition Metal Complexes written by Chengzhong Cui and published by . This book was released on 2010 with total page 300 pages. Available in PDF, EPUB and Kindle. Book excerpt: Atom transfer radical polymerization (ATRP) has been successfully used to prepare well-defined poly(trimethylsilyl)styrenes and the diblock copolymers, poly(trimethylsilyl)styrene-b-polystyrene, with controlled molecular weight and low polydispersity. Quantitative replacement of trimethylsilyl groups with boron tribromide in dichloromethane provided an important highly Lewis acidic intermediate that have allowed for the preparation of novel boron containing borate and boronium types of homopolymers and amphiphilic diblock copolymers with different post-polymerization modification processes. Characterizations including NMR spectroscopy, gel permeation chromatography (GPC) and the representative elemental analysis have been applied to confirm the quantitative transformations from the silylated polymers to the boron containing ionic polymers. The self-assembly properties in block selective solvents of the amphiphilic block copolymers were extensively studied. Most importantly, through an electro-static interaction, the weakly coordinating pentafluorophenyl borate block copolymers were successfully used to attach an organo-rhodium catalyst and then underwent self-assembly in selective solvent to give rise to transition metal containing micelles with well-defined nanostructures. In the last chapter, synthesis and characterizations of a variety of novel multidentate pyridylborate ligands are described. An appropriate procedure for synthesis of 2-pyridyl magnesium chloride in a usual dimeric structure was developed. The 2-pyridyl magnesium chloride was then used to react with different arylbromoboranes in dichloromethane or toluene affording different multidentate ligands. The tris(2-pyridyl)borate ligands were the first pyridine based tripod ligands with a boron atom as the bridging head and their complexation with Fe(II) was studied by cyclic voltammetry (CV) and UV-vis spectroscopy. All the structures of the ligands and metal complexes were determined by single crystal X-ray spectroscopy. The styryltris(2-pyridyl)borate monomer was successfully polymerized in a free radical polymerization to give a polymer with good yield and high molecular weight. NMR analysis was used to confirm the formation of this novel polydentate polymer.

Organometallic Chemistry

Organometallic Chemistry

Author: M Green

Publisher: Royal Society of Chemistry

Published: 2007-10-31

Total Pages: 464

ISBN-13: 1847554202

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Organometallic chemistry is an interdisciplinary science which continues to grow at a rapid pace. Although there is continued interest in synthetic and structural studies the last decade has seen a growing interest in the potential of organometallic chemistry to provide answers to problems in catalysis, synthetic organic chemistry and also in the development of new materials. This Specialist Periodical Report aims to reflect these current interests, reviewing progress in theoretical organometallic chemistry, main group chemistry, the lanthanides and all aspects of transition metal chemistry. Volume 31 covers literature published during 2001. Specialist Periodical Reports provide systematic and detailed review coverage in major areas of chemical research. Compiled by teams of leading authorities in the relevant subject areas, the series creates a unique service for the active research chemist, with regular, in-depth accounts of progress in particular fields of chemistry. Subject coverage within different volumes of a given title is similar and publication is on an annual or biennial basis.


Book Synopsis Organometallic Chemistry by : M Green

Download or read book Organometallic Chemistry written by M Green and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 464 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organometallic chemistry is an interdisciplinary science which continues to grow at a rapid pace. Although there is continued interest in synthetic and structural studies the last decade has seen a growing interest in the potential of organometallic chemistry to provide answers to problems in catalysis, synthetic organic chemistry and also in the development of new materials. This Specialist Periodical Report aims to reflect these current interests, reviewing progress in theoretical organometallic chemistry, main group chemistry, the lanthanides and all aspects of transition metal chemistry. Volume 31 covers literature published during 2001. Specialist Periodical Reports provide systematic and detailed review coverage in major areas of chemical research. Compiled by teams of leading authorities in the relevant subject areas, the series creates a unique service for the active research chemist, with regular, in-depth accounts of progress in particular fields of chemistry. Subject coverage within different volumes of a given title is similar and publication is on an annual or biennial basis.

Handbook Of Boron Science: With Applications In Organometallics, Catalysis, Materials And Medicine (In 4 Volumes)

Handbook Of Boron Science: With Applications In Organometallics, Catalysis, Materials And Medicine (In 4 Volumes)

Author: Narayan S Hosmane

Publisher: World Scientific

Published: 2018-08-07

Total Pages: 1051

ISBN-13: 1786344432

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Boron science features in numerous fields including organic chemistry, organometallic chemistry and medicine. Boron is unique in all aspects of science and engineering and has made a significant impact in our daily lives through its use in fertilizers, germicides, fungicides, soaps, detergents, cancer drugs as well as many household glassware utensils, ceramics and cell phone windows. These volumes bring together an array of internationally renowned scientists to discuss the very latest developments in the application of boron in a broad range of disciplines. This multi-reference work describes the topic by appointing leading researchers to write on current developments in boron science, showcasing its importance to the four separate areas described in each volume: Organometallic Chemistry, Catalysis, Materials Chemistry and Medicine.Written to cover the full range of applications and innovations in boron science, this all-encompassing work offers us a one-stop reference compiled by world-leading researchers and practitioners of the subject, making it perfect for undergraduate and graduate students of chemistry, and researchers and practitioners interested in their professional development.


Book Synopsis Handbook Of Boron Science: With Applications In Organometallics, Catalysis, Materials And Medicine (In 4 Volumes) by : Narayan S Hosmane

Download or read book Handbook Of Boron Science: With Applications In Organometallics, Catalysis, Materials And Medicine (In 4 Volumes) written by Narayan S Hosmane and published by World Scientific. This book was released on 2018-08-07 with total page 1051 pages. Available in PDF, EPUB and Kindle. Book excerpt: Boron science features in numerous fields including organic chemistry, organometallic chemistry and medicine. Boron is unique in all aspects of science and engineering and has made a significant impact in our daily lives through its use in fertilizers, germicides, fungicides, soaps, detergents, cancer drugs as well as many household glassware utensils, ceramics and cell phone windows. These volumes bring together an array of internationally renowned scientists to discuss the very latest developments in the application of boron in a broad range of disciplines. This multi-reference work describes the topic by appointing leading researchers to write on current developments in boron science, showcasing its importance to the four separate areas described in each volume: Organometallic Chemistry, Catalysis, Materials Chemistry and Medicine.Written to cover the full range of applications and innovations in boron science, this all-encompassing work offers us a one-stop reference compiled by world-leading researchers and practitioners of the subject, making it perfect for undergraduate and graduate students of chemistry, and researchers and practitioners interested in their professional development.

Organometallic Chemistry: Volume 44

Organometallic Chemistry: Volume 44

Author: Nathan J Patmore

Publisher: Royal Society of Chemistry

Published: 2022-12-14

Total Pages: 131

ISBN-13: 1839166894

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Providing an invaluable resource, this volume contains analysed, evaluated and distilled information on the latest in organometallic and coordination chemistry research and emerging fields. With continued increases in the variety of information available, researchers can find it difficult to keep up to date with the literature in their field. The reviews in this volume range in scope and include recent developments in homogeneous catalysis for the functionalization of carbon dioxide, early transition metal complexes and their uses in medicinal chemistry, homogeneous gold catalysis under microwave irradiation: a greener approach and properties of metal complexes of mesoionic carbenes. This volume is a key reference for researchers in academic and industrial settings.


Book Synopsis Organometallic Chemistry: Volume 44 by : Nathan J Patmore

Download or read book Organometallic Chemistry: Volume 44 written by Nathan J Patmore and published by Royal Society of Chemistry. This book was released on 2022-12-14 with total page 131 pages. Available in PDF, EPUB and Kindle. Book excerpt: Providing an invaluable resource, this volume contains analysed, evaluated and distilled information on the latest in organometallic and coordination chemistry research and emerging fields. With continued increases in the variety of information available, researchers can find it difficult to keep up to date with the literature in their field. The reviews in this volume range in scope and include recent developments in homogeneous catalysis for the functionalization of carbon dioxide, early transition metal complexes and their uses in medicinal chemistry, homogeneous gold catalysis under microwave irradiation: a greener approach and properties of metal complexes of mesoionic carbenes. This volume is a key reference for researchers in academic and industrial settings.