Organic Reactions in Water

Organic Reactions in Water

Author: U. Marcus Lindstrom

Publisher: John Wiley & Sons

Published: 2008-04-15

Total Pages: 424

ISBN-13: 047099424X

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Volatile organic solvents are the normal media used in both research scale and industrial scale synthesis of organic chemicals. Their environmental impact is significant, however, and so the development of alternative reaction media has become of great interest. Developments in the use of water as a solvent for organic synthesis have reached the point where it could now be considered a viable solvent for many organic reactions. Organic Reactions in Water demonstrates the underlying principles of using water as a reaction solvent and, by reference to a range of reaction types and systems, it’s effective use in synthetic organic chemistry. Written by an internationally respected team of contributors, and with a strong focus on the practical use of water as a reaction medium, this book illustrates the enormous potential of water for the development of new and unique chemistries and synthetic strategies, while at the same time offering a much reduced environmental impact.


Book Synopsis Organic Reactions in Water by : U. Marcus Lindstrom

Download or read book Organic Reactions in Water written by U. Marcus Lindstrom and published by John Wiley & Sons. This book was released on 2008-04-15 with total page 424 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volatile organic solvents are the normal media used in both research scale and industrial scale synthesis of organic chemicals. Their environmental impact is significant, however, and so the development of alternative reaction media has become of great interest. Developments in the use of water as a solvent for organic synthesis have reached the point where it could now be considered a viable solvent for many organic reactions. Organic Reactions in Water demonstrates the underlying principles of using water as a reaction solvent and, by reference to a range of reaction types and systems, it’s effective use in synthetic organic chemistry. Written by an internationally respected team of contributors, and with a strong focus on the practical use of water as a reaction medium, this book illustrates the enormous potential of water for the development of new and unique chemistries and synthetic strategies, while at the same time offering a much reduced environmental impact.

Organic Synthesis in Water

Organic Synthesis in Water

Author: P.A. Grieco

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 321

ISBN-13: 940114950X

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The use of water as a medium for promoting organic reactions has been rather neglected in the development of organic synthesis, despite the fact that it is the solvent in which almost all biochemical processes take place. Chemists have only recently started to appreciate the enormous potential water has to offer in the development of new synthetic reactions and strategies, where it can offer benefits in both unique chemistry and reduced environmental impact. In this new book, the editor, well known for his contribution to the development of water as a useful medium in synthetic organic chemistry, has assembled an international team of authors, themselves at the forefront of research into the use of the unique properties of water carrying out organic transformations, to provide a timely and concise overview of current research. By focusing on the practical use of water in synthetic organic chemistry, and with the concern for the use of solvents in organic chemistry, professional chemists, particularly those involved in industrial research and development, will find this book an essential guide to the current state of the art, and a useful starting point in their own research. Academic chemists, including postgraduate and advanced undergraduate students, will find this book an invaluable guide to this exciting and important area of chemistry.


Book Synopsis Organic Synthesis in Water by : P.A. Grieco

Download or read book Organic Synthesis in Water written by P.A. Grieco and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 321 pages. Available in PDF, EPUB and Kindle. Book excerpt: The use of water as a medium for promoting organic reactions has been rather neglected in the development of organic synthesis, despite the fact that it is the solvent in which almost all biochemical processes take place. Chemists have only recently started to appreciate the enormous potential water has to offer in the development of new synthetic reactions and strategies, where it can offer benefits in both unique chemistry and reduced environmental impact. In this new book, the editor, well known for his contribution to the development of water as a useful medium in synthetic organic chemistry, has assembled an international team of authors, themselves at the forefront of research into the use of the unique properties of water carrying out organic transformations, to provide a timely and concise overview of current research. By focusing on the practical use of water in synthetic organic chemistry, and with the concern for the use of solvents in organic chemistry, professional chemists, particularly those involved in industrial research and development, will find this book an essential guide to the current state of the art, and a useful starting point in their own research. Academic chemists, including postgraduate and advanced undergraduate students, will find this book an invaluable guide to this exciting and important area of chemistry.

Green Organic Reactions

Green Organic Reactions

Author: Gopinathan Anilkumar

Publisher: Springer Nature

Published: 2021-03-27

Total Pages: 349

ISBN-13: 9813368977

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This book presents important developments and applications of green chemistry, especially in the field of organic chemistry. The chapters give a brief account of green organic reactions in water, green organic reactions using microwave and in solvent-free conditions. In depth discussions on the green aspects of ionic liquids, flow reactions, and recoverable catalysts are provided in this book. An exclusive chapter devoted to green Lewis acid is also included. The potential of supercritical fluids as green solvents in various areas of organic reactions is explained as well. This book will be a valuable reference for beginners as well as advanced researchers interested in green organic chemistry.


Book Synopsis Green Organic Reactions by : Gopinathan Anilkumar

Download or read book Green Organic Reactions written by Gopinathan Anilkumar and published by Springer Nature. This book was released on 2021-03-27 with total page 349 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents important developments and applications of green chemistry, especially in the field of organic chemistry. The chapters give a brief account of green organic reactions in water, green organic reactions using microwave and in solvent-free conditions. In depth discussions on the green aspects of ionic liquids, flow reactions, and recoverable catalysts are provided in this book. An exclusive chapter devoted to green Lewis acid is also included. The potential of supercritical fluids as green solvents in various areas of organic reactions is explained as well. This book will be a valuable reference for beginners as well as advanced researchers interested in green organic chemistry.

Solvents as Reagents in Organic Synthesis

Solvents as Reagents in Organic Synthesis

Author: Xiao-Feng Wu

Publisher: John Wiley & Sons

Published: 2018-01-03

Total Pages: 552

ISBN-13: 352734196X

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Written by highly renowned and experienced authors, this is the only reference on the application of solvents as reagents. Clearly structured, the text describes various methods for the activation and reaction of these small molecules, highlighting the synthetic opportunities as well as process-oriented advantages. To this end, all relevant types of solvents are covered separately and emphasized with numerous synthetic examples, while taking care to explain applications so as to avoid undesired side reactions. The result is a unique resource for every synthetic chemist and reaction engineer in industry and academia working on the methodical optimization of synthetic transformations.


Book Synopsis Solvents as Reagents in Organic Synthesis by : Xiao-Feng Wu

Download or read book Solvents as Reagents in Organic Synthesis written by Xiao-Feng Wu and published by John Wiley & Sons. This book was released on 2018-01-03 with total page 552 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written by highly renowned and experienced authors, this is the only reference on the application of solvents as reagents. Clearly structured, the text describes various methods for the activation and reaction of these small molecules, highlighting the synthetic opportunities as well as process-oriented advantages. To this end, all relevant types of solvents are covered separately and emphasized with numerous synthetic examples, while taking care to explain applications so as to avoid undesired side reactions. The result is a unique resource for every synthetic chemist and reaction engineer in industry and academia working on the methodical optimization of synthetic transformations.

Basic Techniques of Preparative Organic Chemistry

Basic Techniques of Preparative Organic Chemistry

Author: William Sabel

Publisher: Elsevier

Published: 2013-09-03

Total Pages: 207

ISBN-13: 1483213773

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Basic Techniques of Preparative Organic Chemistry covers a detailed guide for carrying out the procedures commonly needed in preparative organic chemistry. The book discusses the nature of organic reactions; the basic principles of preparative organic chemistry; unit operations; and good laboratory practice. The text then provides a review of apparatus and equipment and describes the potential hazards involved in a chemical operation, such as toxicity, bodily injuries, smoking, fire, explosion, and implosion. Techniques and unit operations for carrying out a reaction and for isolating and purifying a reaction product; and the criteria for and methods of assessing purity are also considered. The book further tackles packing and storing products and samples and making reports and communications. Students taking organic chemistry courses will find the text useful.


Book Synopsis Basic Techniques of Preparative Organic Chemistry by : William Sabel

Download or read book Basic Techniques of Preparative Organic Chemistry written by William Sabel and published by Elsevier. This book was released on 2013-09-03 with total page 207 pages. Available in PDF, EPUB and Kindle. Book excerpt: Basic Techniques of Preparative Organic Chemistry covers a detailed guide for carrying out the procedures commonly needed in preparative organic chemistry. The book discusses the nature of organic reactions; the basic principles of preparative organic chemistry; unit operations; and good laboratory practice. The text then provides a review of apparatus and equipment and describes the potential hazards involved in a chemical operation, such as toxicity, bodily injuries, smoking, fire, explosion, and implosion. Techniques and unit operations for carrying out a reaction and for isolating and purifying a reaction product; and the criteria for and methods of assessing purity are also considered. The book further tackles packing and storing products and samples and making reports and communications. Students taking organic chemistry courses will find the text useful.

Modern Solvents in Organic Synthesis

Modern Solvents in Organic Synthesis

Author: Paul Knochel

Publisher: Springer

Published: 2003-07-01

Total Pages: 217

ISBN-13: 354048664X

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In recent years the choice of a given solvent for performing a reaction has become increasingly important. More and more, selective reagents are used for chemical transformations and the choice of the solvent may be determining for reaching high reaction rates and high selectivities. The toxicity and recycling considerations have also greatly influenced the nature of the solvents used for industrial reactions. Thus, the development of reactions in water is not only important on the laboratory scale but also for industrial applications. The p- formance of metal-catalyzed reactions in water for example has led to several new hydrogenation or hydroformylation procedures with important industrial applications. The various aspects of organic chemistry in water will be prese- ed in this book. Recently, novel reaction media such as perfluorinated solvents or supercritical carbon dioxide has proven to have unique advantages leading to more practical and more efficient reactions. Especially with perfluorinated solvents, new biphasic catalyses and novel approaches to perform organic reactions have been developed. These aspects will be examined in detail in this volume. Finally, the performance of reactions in the absence of solvents will show practical alternatives for many reactions. More than ever before, the choice of the solvent or the solvent system is ess- tial for realizing many chemical transformations with the highest efficiency. This book tries to cover the more recent and important new solvents or solvent systems for both academic and industrial applications.


Book Synopsis Modern Solvents in Organic Synthesis by : Paul Knochel

Download or read book Modern Solvents in Organic Synthesis written by Paul Knochel and published by Springer. This book was released on 2003-07-01 with total page 217 pages. Available in PDF, EPUB and Kindle. Book excerpt: In recent years the choice of a given solvent for performing a reaction has become increasingly important. More and more, selective reagents are used for chemical transformations and the choice of the solvent may be determining for reaching high reaction rates and high selectivities. The toxicity and recycling considerations have also greatly influenced the nature of the solvents used for industrial reactions. Thus, the development of reactions in water is not only important on the laboratory scale but also for industrial applications. The p- formance of metal-catalyzed reactions in water for example has led to several new hydrogenation or hydroformylation procedures with important industrial applications. The various aspects of organic chemistry in water will be prese- ed in this book. Recently, novel reaction media such as perfluorinated solvents or supercritical carbon dioxide has proven to have unique advantages leading to more practical and more efficient reactions. Especially with perfluorinated solvents, new biphasic catalyses and novel approaches to perform organic reactions have been developed. These aspects will be examined in detail in this volume. Finally, the performance of reactions in the absence of solvents will show practical alternatives for many reactions. More than ever before, the choice of the solvent or the solvent system is ess- tial for realizing many chemical transformations with the highest efficiency. This book tries to cover the more recent and important new solvents or solvent systems for both academic and industrial applications.

Biphasic Chemistry and The Solvent Case

Biphasic Chemistry and The Solvent Case

Author: Jean-Philippe Goddard

Publisher: John Wiley & Sons

Published: 2020-02-05

Total Pages: 230

ISBN-13: 1786305097

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Biphasic Chemistry and The Solvent Case examines recent improvements in reaction conditions, in order to affirm the role of chemistry in the sustainable field. This book shows that those who work within the chemistry industry support limits for the use of toxic or flammable solvents, since it reduces the purifications to simple filtrations. Thanks to commercial scavengers, solid phase syntheses are now available to all. Fluorine biphasic catalysis enables extremely efficient catalyst recycling and has a high applicability potential at the industrial level. This book also reviews the many studies that have shown that water is a solvent of choice for most synthetic reactions. Particular traits can be obtained and the effects on thermodynamics make it possible to operate at lower temperatures, thereby achieving energy savings. Finally the great diversity of application of the reactions without solvents is illustrated.


Book Synopsis Biphasic Chemistry and The Solvent Case by : Jean-Philippe Goddard

Download or read book Biphasic Chemistry and The Solvent Case written by Jean-Philippe Goddard and published by John Wiley & Sons. This book was released on 2020-02-05 with total page 230 pages. Available in PDF, EPUB and Kindle. Book excerpt: Biphasic Chemistry and The Solvent Case examines recent improvements in reaction conditions, in order to affirm the role of chemistry in the sustainable field. This book shows that those who work within the chemistry industry support limits for the use of toxic or flammable solvents, since it reduces the purifications to simple filtrations. Thanks to commercial scavengers, solid phase syntheses are now available to all. Fluorine biphasic catalysis enables extremely efficient catalyst recycling and has a high applicability potential at the industrial level. This book also reviews the many studies that have shown that water is a solvent of choice for most synthetic reactions. Particular traits can be obtained and the effects on thermodynamics make it possible to operate at lower temperatures, thereby achieving energy savings. Finally the great diversity of application of the reactions without solvents is illustrated.

Green Approaches in Medicinal Chemistry for Sustainable Drug Design

Green Approaches in Medicinal Chemistry for Sustainable Drug Design

Author: Bimal Krishna Banik

Publisher: Elsevier

Published: 2024-05-31

Total Pages: 699

ISBN-13: 0443161674

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Extensive experimentation and high failure rates are a well-recognized downside to the drug discovery process, with the resultant high levels of inefficiency and waste producing a negative environmental impact. Sustainable and Green Approaches in Medicinal Chemistry 2e reveals how medicinal chemistry can play a direct role in addressing this issue. After providing essential context to the growth of green chemistry in relation to drug discovery, the book goes on to identify a broad range of practical techniques and useful insights, revealing how medicinal chemistry techniques can be used to improve efficiency, mitigate failure and increase the environmental benignity of the entire drug discovery process. Drawing on the knowledge of a global team of experts, Sustainable and Green Approaches in Medicinal Chemistry, Second Edition encourages the growth of green medicinal chemistry, and supports medicinal chemists, drug discovery researchers, pharmacologists and all those in related fields across both academia and industry in integrating these approaches into their own work. This second volume of the second edition includes the development of nanoparticles and nanocomposites, as well as the application of ultrasound and microwave-induced methods; studies solventless synthesis; defines the role of steroids; studies reactions in aqueous solution; identifies enzyme-mediated reactions; investigates ionic liquids and deep eutectic solvents; explores natural products; investigates solid supports; realizes the effects of salts; focuses on combinatorial chemistry; develops one-pot methods; analyzes multi-component reactions; investigates dipole moment values; and examines computer-assisted methods. Highlights the need for adoption of sustainable and green chemistry pathways in drug development Reveals risk factors associated with the drug development process and the ways sustainable approaches can help address these Identifies novel and cost effective green medicinal chemistry approaches for improved efficiency and sustainability


Book Synopsis Green Approaches in Medicinal Chemistry for Sustainable Drug Design by : Bimal Krishna Banik

Download or read book Green Approaches in Medicinal Chemistry for Sustainable Drug Design written by Bimal Krishna Banik and published by Elsevier. This book was released on 2024-05-31 with total page 699 pages. Available in PDF, EPUB and Kindle. Book excerpt: Extensive experimentation and high failure rates are a well-recognized downside to the drug discovery process, with the resultant high levels of inefficiency and waste producing a negative environmental impact. Sustainable and Green Approaches in Medicinal Chemistry 2e reveals how medicinal chemistry can play a direct role in addressing this issue. After providing essential context to the growth of green chemistry in relation to drug discovery, the book goes on to identify a broad range of practical techniques and useful insights, revealing how medicinal chemistry techniques can be used to improve efficiency, mitigate failure and increase the environmental benignity of the entire drug discovery process. Drawing on the knowledge of a global team of experts, Sustainable and Green Approaches in Medicinal Chemistry, Second Edition encourages the growth of green medicinal chemistry, and supports medicinal chemists, drug discovery researchers, pharmacologists and all those in related fields across both academia and industry in integrating these approaches into their own work. This second volume of the second edition includes the development of nanoparticles and nanocomposites, as well as the application of ultrasound and microwave-induced methods; studies solventless synthesis; defines the role of steroids; studies reactions in aqueous solution; identifies enzyme-mediated reactions; investigates ionic liquids and deep eutectic solvents; explores natural products; investigates solid supports; realizes the effects of salts; focuses on combinatorial chemistry; develops one-pot methods; analyzes multi-component reactions; investigates dipole moment values; and examines computer-assisted methods. Highlights the need for adoption of sustainable and green chemistry pathways in drug development Reveals risk factors associated with the drug development process and the ways sustainable approaches can help address these Identifies novel and cost effective green medicinal chemistry approaches for improved efficiency and sustainability

Organic Synthesis in Water

Organic Synthesis in Water

Author: P.A. Grieco

Publisher: Springer

Published: 2014-04-20

Total Pages: 310

ISBN-13: 9789401060776

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The use of water as a medium for promoting organic reactions has, for the most part, been non-existent, despite the fact that water has served, and continues to serve, as the solvent in which the vast majority of biochemical processes take place. Chemists have only recently come to appreciate the enormous potential that water holds for those engaged in synthetic organic and organometallic chemistry, in part because of water's unique enthalpic and entropic properties. In this volume, an international team of authors, each taking advantage of the unique properties of water for carrying out organic transformations, is brought together in order to provide a timely and concise overview of current research. The chapters focus on the practical use of water in synthetic organic chemistry, with special emphasis on Diels-Alder reactions, Claisen rearrangements, organometallic chemistry, transition-metal catalysis, oxida tions and reductions. I am grateful to my colleagues, J. Auge, I. Beletskaya, A. Cheprakov, F. Fringuelli, J. Gajewski, P. Gamer, S. Kobayashi, A. Lubineau, D. Parker, O. Piermatti, F. Pizzo and Y. Queneau, for participating in this venture. Their knowledge and experience have been invaluable in putting this volume together.


Book Synopsis Organic Synthesis in Water by : P.A. Grieco

Download or read book Organic Synthesis in Water written by P.A. Grieco and published by Springer. This book was released on 2014-04-20 with total page 310 pages. Available in PDF, EPUB and Kindle. Book excerpt: The use of water as a medium for promoting organic reactions has, for the most part, been non-existent, despite the fact that water has served, and continues to serve, as the solvent in which the vast majority of biochemical processes take place. Chemists have only recently come to appreciate the enormous potential that water holds for those engaged in synthetic organic and organometallic chemistry, in part because of water's unique enthalpic and entropic properties. In this volume, an international team of authors, each taking advantage of the unique properties of water for carrying out organic transformations, is brought together in order to provide a timely and concise overview of current research. The chapters focus on the practical use of water in synthetic organic chemistry, with special emphasis on Diels-Alder reactions, Claisen rearrangements, organometallic chemistry, transition-metal catalysis, oxida tions and reductions. I am grateful to my colleagues, J. Auge, I. Beletskaya, A. Cheprakov, F. Fringuelli, J. Gajewski, P. Gamer, S. Kobayashi, A. Lubineau, D. Parker, O. Piermatti, F. Pizzo and Y. Queneau, for participating in this venture. Their knowledge and experience have been invaluable in putting this volume together.

Organic Radical Reactions in Water and Alternative Media

Organic Radical Reactions in Water and Alternative Media

Author: J. Alberto Postigo

Publisher:

Published: 2011

Total Pages: 0

ISBN-13: 9781612096483

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This book discusses and presents current research in the study of radical reactions of synthetic utility in water and non-conventional media. Emphasis is made throughout the book on synthetic methods, not covering other important aspects of radical chemistry in water, such as computational studies aimed at clarifying the powerful effect of water as a selective solvating media for radical chemistry, and reasons for the higher selectivity and reaction yields when water is employed as a solvent.


Book Synopsis Organic Radical Reactions in Water and Alternative Media by : J. Alberto Postigo

Download or read book Organic Radical Reactions in Water and Alternative Media written by J. Alberto Postigo and published by . This book was released on 2011 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book discusses and presents current research in the study of radical reactions of synthetic utility in water and non-conventional media. Emphasis is made throughout the book on synthetic methods, not covering other important aspects of radical chemistry in water, such as computational studies aimed at clarifying the powerful effect of water as a selective solvating media for radical chemistry, and reasons for the higher selectivity and reaction yields when water is employed as a solvent.